72020

Sodium tetraphenylborate

puriss. p.a., ACS reagent, ≥99.5% (NT)

• 동의어(들): Tetraphenylboron sodium
• Linear Formula: (C₆H₅)₄BNa
• CAS Number: 143-66-8
• Molecular Weight: 342.22
• Beilstein: 3599783
• EC Number: 205-605-5
• MDL number: MFCD00011494
• UNSPSC 코드: 12352100
• PubChem Substance ID: 57652389
• NACRES: NA.21

속성

• Grade: ACS reagent
• Quality Level: 200
• grade: puriss. p.a.
• 분석: ≥99.5% (NT)
• 양식: solid
• 손실: ≤0.5% loss on drying, 110 °C
• 음이온 미량물: chloride (Cl^-): ≤50 mg/kg; sulfate (SO₄^2-): ≤50 mg/kg
• 양이온 미량물: Ca: ≤100 mg/kg; Cd: ≤5 mg/kg; Co: ≤5 mg/kg; Cr: ≤5 mg/kg; Cu: ≤5 mg/kg; Fe: ≤5 mg/kg; K: ≤500 mg/kg; Mg: ≤5 mg/kg; Mn: ≤5 mg/kg; Ni: ≤5 mg/kg; Pb: ≤5 mg/kg; Zn: ≤5 mg/kg
• SMILES string: [Na+].c1ccc(cc1)[B-](c2ccccc2)(c3ccccc3)c4ccccc4
• InChI: 1S/C24H20B.Na/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;/q-1;+1
• InChI key: HFSRCEJMTLMDLI-UHFFFAOYSA-N

설명

일반 설명

Sodium tetraphenylborate (Ph₄BNa) undergoes rhodium-catalyzed addition reactions with N-phenylsulfonyl aldimines to afford R(Ph)CHNHSO₂Ph.[1]

애플리케이션

Sodium tetraphenylborate (Ph₄BNa) may be used in the synthesis of polyfunctional biaryls via modified Suzuki cross-coupling reaction.[2] It may be employed as a derivatization reagent for the analysis of methylmercury and ethylmercury by gas chromatography (GC) coupled with atomic fluorescence spectrometry (AFS), microwave-induced plasma atomic emission spectrometry (AES) and mass spectrometry (MS).[3]

기타 정보

Reagent for the precipitation and titration of potassium[4][5]; For the amperometric titration of amines, quaternary ammonium compounds and potassium[6]; For the titration of quaternary ammonium surfactants[7]; Titrant for amines and NH₄Cl in the presence of a K selective electrode[8]

안전성 정보

• 픽토그램: GHS06
• 신호어: Danger
• 유해 및 위험 성명서: H301
• 예방조치 성명서: P264 - P270 - P301 + P310 - P405 - P501
• Hazard Classifications: Acute Tox. 3 Oral
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Faceshields, Gloves