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Merck
모든 사진(1)

문서

15512

Sigma-Aldrich

Formaldehyde solution

meets analytical specification of USP, ≥34.5 wt. %

동의어(들):

Formalin

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About This Item

Linear Formula:
HCHO
CAS Number:
Molecular Weight:
30.03
Beilstein:
1209228
MDL number:
UNSPSC 코드:
12352114
eCl@ss:
39021101
PubChem Substance ID:
NACRES:
NA.21

vapor density

1.03 (vs air)

Quality Level

vapor pressure

52 mmHg ( 37 °C)

autoignition temp.

572 °F

품질

meets analytical specification of USP

포함

9.0-15.0% methanol as stabilizer (GC)

농도

≥34.5 wt. %
25-50%

불순물

acidic reac. substances, complies
residual solvents, complies

무기 잔류물

≤0.01% (as SO4)

density

1.09 g/mL at 25 °C (lit.)

적합성

corresponds for identity

SMILES string

[H]C([H])=O

InChI

1S/CH2O/c1-2/h1H2

InChI key

WSFSSNUMVMOOMR-UHFFFAOYSA-N

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관련 카테고리

일반 설명

Formaldehyde solution commercially formaldehyde solution is an aqueous solution containing 37% formaldehyde and 8-10% methanol. Formaldehyde solution can be activated by adding the catalytic amount of lanthanide triflate. This activated formaldehyde solution was employed for the smooth hydroxymethylation reaction of silyl enol ethers. Formaldehyde solution reacts with silyl enol ethers to afford the corresponding hydroxymethylated adducts in high yields.

애플리케이션

Formaldehyde solution was used to prepare the formaldehyde stock solution for the development of transparent sol-gels with entrapped sensitive and selective reagents for the detection of formaldehyde in air. It may be used in the preparation of nanocrystalline metal (Cu, Hg, Zn, Bi, Pb) sulfides having different shapes and different particle sizes.

기타 정보

The article number 15512-4X2.5L-R will be discontinued. Please order the single bottle 15512-2.5L-R which is physically identical with the same exact specifications.
The article number 15512-6X1L-R will be discontinued. Please order the single bottle 15512-1L-R which is physically identical with the same exact specifications.

픽토그램

Skull and crossbonesHealth hazardCorrosion

신호어

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 1 - STOT SE 3

표적 기관

Eyes,Central nervous system, Respiratory system

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point (°F)

143.6 °F - closed cup

Flash Point (°C)

62 °C - closed cup


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문서 라이브러리 방문

이미 열람한 고객

Microwave synthesis of nanocrystalline metal sulfides in formaldehyde solution.
Liao X-H, et al.
Materials Science and Engineering, B, 85(1), 85-89 (2001)
Lanthanide Trifluoromethanesulfonates as Stable Lewis Acids in Aqueous Media. Yb (OTf)3 Catalyzed Hydroxymethylation Reaction of Silyl Enol Ethers with Commercial Formaldehyde Solution.
Kobayashi S.
Chemistry Letters (Jpn), 12, 2187-2190 (1991)
Lanthanide triflates as water-tolerant Lewis acids. Activation of commercial formaldehyde solution and use in the aldol reaction of silyl enol ethers with aldehydes in aqueous media.
Kobayashi S and Hachiya I.
The Journal of Organic Chemistry, 59(13), 3590-3596 (1994)
Opas Bunkoed et al.
Analytica chimica acta, 659(1-2), 251-257 (2010-01-28)
We report the development of transparent sol-gels with entrapped sensitive and selective reagents for the detection of formaldehyde. The sampling method is based on the adsorption of formaldehyde from the air and reaction with beta-diketones (for example acetylacetone) in a
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