1.13364

Tetrahydrofuran-d₈

deuteration degree min 99.5% for NMR spectroscopy MagniSolv^™

• 동의어(들): THF deuterated, Deuterated tetrahydrofuran, Octadeuterotetrahydrofuran
• 실험식(Hill 표기법): C₄D₈O
• CAS Number: 1693-74-9
• Molecular Weight: 80.16
• Beilstein: 111854
• MDL number: MFCD00044238
• UNSPSC 코드: 12142201
• EC 인덱스 번호: 216-898-4
• NACRES: NA.22

속성

• Quality Level: 200
• 형태: liquid
• autoignition temp.: 215 °C
• 효능: 1650 mg/kg LD₅₀, oral (Rat)
• 기술: NMR: suitable
• 불순물: ≤0.030% Water (H<SUB>2</SUB>O) (NMR); ≤0.050% Water (H<SUB>2</SUB>O) (Karl Fischer)
• refractive index: n20/D 1.403 (lit.)
• bp: 65-66 °C (lit.)
• mp: −106 °C (lit.)
• 전이 온도: flash point -17.5 °C
• density: 0.985 g/mL at 25 °C (lit.)
• 질량 이동: M+8
• 저장 온도: 2-8°C
• SMILES string: [2H]C1([2H])OC([2H])([2H])C([2H])([2H])C1([2H])[2H]
• InChI: 1S/C4H8O/c1-2-4-5-3-1/h1-4H2/i1D2,2D2,3D2,4D2
• InChI key: WYURNTSHIVDZCO-SVYQBANQSA-N

설명

일반 설명

A wide range of MagniSolv deuterated solvents with extremely low residual water, excellent chemical purity, and the highest isotopic enrichment available can satisfy the most demanding requirements of researchers. Depending on application and sensitivity of the NMR spectrometer our offer solvents with deuteration degrees between 98% and 99.96%. In case of all the water soluble deuterated standard products, water content is specified according to both Karl Fischer and NMR.

애플리케이션

• Experimental and Theoretical Study of CO2 Insertion into Ruthenium Hydride Complexes.: This research provides insights into the mechanistic pathways for CO2 reactivity with ruthenium hydride complexes, potentially relevant for catalytic applications including transformations involving Tetrahydrofuran-d₈ (Ramakrishnan et al., 2016).



• Syntheses, structures, and NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds.: Details the synthesis and structural characterization of trimethyltin compounds, useful for understanding the coordination chemistry that may involve Tetrahydrofuran-d₈ as a solvent or structural analogue (Lichtscheidl et al., 2015).



• NMR studies of coupled low- and high-barrier hydrogen bonds in pyridoxal-5′-phosphate model systems in polar solution.: Discusses the application of NMR spectroscopy in studying hydrogen bonding interactions, where Tetrahydrofuran-d₈ could be utilized as a deuterated solvent for enhanced spectral clarity (Sharif et al., 2007).



• Stable hydrocarbon diradical, an analogue of trimethylenemethane.: Investigates stable hydrocarbon diradicals, where Tetrahydrofuran-d₈ may be used as part of the experimental setup to stabilize reactive intermediates or as a solvent to study radical stability (Rajca et al., 2005).

분석 메모

Deuteration degree: ≥ 99.50 %
Water (NMR, H₂O): ≤ 0.030 %
Performance test (NMR-spectrum): passes test
Water (K. Fischer, H₂O + D₂O): ≤ 0.050 %

추천 제품

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법적 정보

MAGNISOLV is a trademark of Merck KGaA, Darmstadt, Germany

안전성 정보

• 픽토그램: GHS02,GHS07,GHS08
• 신호어: Danger
• 유해 및 위험 성명서: H225 - H302 - H319 - H335 - H336 - H351
• 예방조치 성명서: P202 - P210 - P233 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2
• 보충제 위험성: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 1
• Flash Point (°F): 1.4 °F - closed cup
• Flash Point (°C): -17 °C - closed cup