M27301

Methyl acrylate

99%, contains ≤100 ppm monomethyl ether hydroquinone as inhibitor

• 동의어(들): Methylacrylate
• Linear Formula: CH₂=CHCOOCH₃
• CAS Number: 96-33-3
• Molecular Weight: 86.09
• Beilstein: 605396
• EC Number: 202-500-6
• MDL number: MFCD00008627
• UNSPSC 코드: 12162002
• PubChem Substance ID: 24896758
• NACRES: NA.23

속성

• vapor density: 3 (vs air)
• Quality Level: 200
• vapor pressure: 67.5 mmHg ( 20 °C)
• 분석: 99%
• 형태: liquid
• autoignition temp.: 874 °F
• 포함: ≤100 ppm monomethyl ether hydroquinone as inhibitor
• expl. lim.: 14.5 %
• refractive index: n20/D 1.402 (lit.)
• bp: 80 °C (lit.)
• mp: −75 °C (lit.)
• density: 0.956 g/mL at 25 °C (lit.)
• 저장 온도: 2-8°C
• SMILES string: COC(=O)C=C
• InChI: 1S/C4H6O2/c1-3-4(5)6-2/h3H,1H2,2H3
• InChI key: BAPJBEWLBFYGME-UHFFFAOYSA-N

설명

일반 설명

Methyl acrylate is an acrylic monomer. It is useful in the preparation of polymers having rigid, flexible, ionic, nonionic, hydrophobic, or hydrophilic properties. Mechanism of the copolymerization of ethylene and α-olefins with methyl acrylate has been studied. Heck reaction of iodobenzene with methyl acrylate in the presence of triethylamine and sodium carbonate has been reported. The reversible addition fragmentation chain transfer (RAFT) bulk polymerization of methyl acrylate using 1-phenylethyl dithiobenzoate and 2-(2-cyanopropyl) dithiobenzoate (RAFT agents) has been studied. Reactive intermediates formed during the Heck reaction of methyl acrylate have been characterized by NMR spectroscopy.

애플리케이션

Methyl acrylate was used in the preparation of poly(methyl acrylate) elastomers. It was also used in the synthesis of α,ω-dicarboxylic acid esters.

안전성 정보

• 픽토그램: GHS02,GHS06
• 신호어: Danger
• 유해 및 위험 성명서: H225,H302 + H312,H315,H317,H319,H331,H335,H412
• 예방조치 성명서: P210 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point (°F): 27.0 °F - closed cup
• Flash Point (°C): -2.8 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter