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Merck
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주요 문서

935654

Sigma-Aldrich

Tris(trimethylsilyl) borate

greener alternative

≥99.5%, battery grade

동의어(들):

Boric acid tris(trimethylsilyl) ester, TMSB, Tris(trimethylsiloxy)borane, Tris(trimethylsiloxy)boron

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935654-50G
₩298,715

₩298,715


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935654-50G
₩298,715

About This Item

Linear Formula:
[(CH3)3SiO]3B
CAS Number:
Molecular Weight:
278.38
Beilstein:
1772733
MDL number:
UNSPSC 코드:
12352005

₩298,715


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벌크 견적 요청

Grade

battery grade

Quality Level

설명

Application: Battery manufacturing

분석

≥99.5%

양식

(Colorless liquid)

환경친화적 대안 제품 특성

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

refractive index

n20/D 1.386 (lit.)

bp

186 °C (lit.)
186 °C

mp

-35 °C

density

0.831 g/mL at 25 °C (lit.)

응용 분야

battery manufacturing

환경친화적 대안 카테고리

SMILES string

C[Si](C)(C)OB(O[Si](C)(C)C)O[Si](C)(C)C

InChI

1S/C9H27BO3Si3/c1-14(2,3)11-10(12-15(4,5)6)13-16(7,8)9/h1-9H3

InChI key

YZYKZHPNRDIPFA-UHFFFAOYSA-N

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일반 설명

Tris(trimethylsilyl) borate (TMSB) is an electron-deficient organoborate compound. It is a colorless liquid that that is miscible with many organic solvents, including the linear and cyclic carbonates used in battery applications. Our battery grade TMSB is differentiated by its high purity and low trace water content to ensure consistent and reliable performance in batteries.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

애플리케이션

Tris(trimethylsilyl) borate has a wide range of applications in various industries, including battery manufacturing, where it is used as an electrolyte additive, particularly in high-voltage lithium-ion batteries. TMSB is a cathode-film-forming additive that forms a thin protective coating called a solid-electrolyte interface (SEI) on the surface of the cathode. Adding TMSB to the electrolyte formulation, even at low concentrations of 0.5 wt.%, noticeably improves capacity retention for NMC, LMO, and LMNO cathodes.[1][2][3] TMSB also is shown to reduce the flammability of the electrolyte and improve the thermal stability of LiPF6-based electrolytes at elevated temperatures.[3]
TMSB also has catalytic properties, which make it useful in organic synthesis reactions and as a reagent in the manufacturing of pharmaceuticals and other chemicals.

관련 제품

제품 번호
설명
가격

픽토그램

FlameExclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

105.8 °F - closed cup

Flash Point (°C)

41 °C - closed cup


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문서 라이브러리 방문

Effect of tris(trimethylsilyl)borate on the high voltage capacity retention of LiNi0.5Co0.2Mn0.3O2/graphite cells
Zuo X, et al.
Journal of Power Sources, 229, 308-312 (2013)
Tris(trimethylsilyl)borate as an electrolyte additive for improving interfacial stability of high voltage layered lithium-rich oxide cathode/carbonate-based electrolyte
Li J, et al
Journal of Power Sources, 285, 360-366 (2015)
Tris(trimethylsilyl) borate as an electrolyte additive to improve the cyclability of LiMn2O4cathode for lithium-ion battery
Liu Y, et al.
Journal of Power Sources, 221, 90-96 (2013)

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