906263
cis-(+)-Limonene oxide
동의어(들):
(+)-cis-Limonene-1,2-epoxide, (1R,4R,6S)-1-methyl-4-(1-methylethenyl)-7-oxabicyclo[4.1.0]heptane, cis-(+)-1,2-Epoxy-p-menth-8-ene
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모든 사진(2)
About This Item
실험식(Hill 표기법):
C10H16O
CAS Number:
Molecular Weight:
152.23
MDL number:
UNSPSC 코드:
12352212
NACRES:
NA.22
추천 제품
양식
liquid
density
0.932 g/mL
SMILES string
O1[C@@]2([C@H]1C[C@H](CC2)C(=C)C)C
InChI
1S/C10H16O/c1-7(2)8-4-5-10(3)9(6-8)11-10/h8-9H,1,4-6H2,2-3H3/t8-,9+,10-/m0/s1
InChI key
CCEFMUBVSUDRLG-AEJSXWLSSA-N
애플리케이션
cis-(+)-Limonene oxide can be used as:
- A monomer to prepare poly(limonene)carbonate by Al(III) catalyzed coupling reaction with CO2.
- A reactant to prepare trans-diaxial diol via diastereoselective ring-opening reaction using molybdenum complex catalyst.
- A reactant to synthesize trans-dihydrocarvone via isomerization reaction in the presence of silica-supported tungstophosphoric acid as a catalyst and dialkylcarbonate as a green solvent.
cis-(+)-Limonene oxide is a valuable chiral terpene oxide building block.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point (°F)
160.7 °F
Flash Point (°C)
71.5 °C
Leticia Peña Carrodeguas et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(16), 6115-6122 (2015-03-05)
Amino-triphenolate derived Al(III) complexes combined with suitable nucleophiles have been investigated as binary catalysts for the coupling of limonene oxide and carbon dioxide to afford alternating polycarbonates. These catalysts are able to produce stereoregular, perfectly alternating trans-polymers from cis-limonene oxide
Heteropoly acid catalysis for the isomerization of biomass-derived limonene oxide and kinetic separation of the trans-isomer in green solvents
Cotta RF, et al.
Applied Catalysis A: General, 584, 117173-117173 (2019)
Diastereoselective ring opening of limonene oxide with water catalysed by β-ketophosphonate complexes of molybdenum(VI)
Salles L,et al.
Tetrahedron Asymmetry, 10(8), 1471-1476 (1999)
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