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Merck
모든 사진(1)

문서

901223

Sigma-Aldrich

3-(Trimethylsilyl)propargyl methacrylate

≥98.0%, contains 200 ppm MEHQ as inhibitor

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About This Item

실험식(Hill 표기법):
C10H16O2Si
CAS Number:
Molecular Weight:
196.32
MDL number:
UNSPSC 코드:
12162002

분석

≥98.0%

형태

liquid

포함

200 ppm MEHQ as inhibitor

색상

colorless to pale yellow

배송 상태

wet ice

저장 온도

−20°C

일반 설명

3-(Trimethylsilyl)propargyl methacrylate is a methacrylate-based monomer for use in the synthesis of alkyne-functionalized polymers and copolymers. The incorporation of alkynes allows for rapid post-polymerization modification through reactions, such as copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) or thiol-yne click reactions. These reactions are highly preferable for functionalization due their high efficiency and the ability to easily install the corresponding functionality (e.g., azides or thiols) onto the biomolecule or small molecule of interest. While alkynes offer great promise for post-polymerization functionalization, it is difficult to polymerize bifunctional, alkyne-containing monomers without the synthesis of branched or highly gelled products. 3-(Trimethylsilyl)propargyl methacrylate features a silyl-protected alkyne that can be easily deprotected post-polymerization to yield alkyne-functionalized polymers and copolymers.

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

193.1 °F

Flash Point (°C)

89.5 °C


시험 성적서(COA)

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문서 라이브러리 방문

Graft block copolymers of propargyl methacrylate and vinyl acetate via a combination of RAFT/MADIX and click chemistry: Reaction analysis.
Quemener, D. et al
Journal of Polymer Science Part A: Polymer Chemistry, 46, 155-173 (2008)
Vincent Ladmiral et al.
Journal of the American Chemical Society, 128(14), 4823-4830 (2006-04-06)
The synthesis of novel well-defined alkyne side chain functional polymers featuring narrow molecular weight distributions (PDI = 1.09-1.17) by living radical polymerization is described. Grafting of protected and unprotected carbohydrates is achieved via either a C-6 or an anomeric azide
Clickable initiators, monomers and polymers in controlled radical polymerizations?a prospective combination in polymer science.
Mansfeld, U. et al
Polym. Chem., 1, 1560-1598 (2010)

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