900715

N-((S)-1-((4S,5S)-4-Benzyl-5-phenyl-4,5-dihydrooxazol-2-yl)-2,2-dimethylpropyl)acetamide

• 동의어(들): Chiral MPAO ligand
• 실험식(Hill 표기법): C₂₃H₂₈N₂O₂
• CAS Number: 2079094-32-7
• Molecular Weight: 364.48
• UNSPSC 코드: 12161600
• NACRES: NA.22

속성

• 분석: ≥95%
• 양식: powder or crystals
• 반응 적합성: reaction type: C-C Bond Formation; reagent type: catalyst; reagent type: ligand; reaction type: C-H Activation
• mp: 130 °C
• 작용기: amide; phenyl
• 저장 온도: 2-8°C

설명

애플리케이션

N-((S)-1-((4S,5S)-4-Benzyl-5-phenyl-4,5-dihydrooxazol-2-yl)-2,2-dimethylpropyl)acetamide is a chiral ligand developed by Jin-Quan Yu′s lab for Pd(II)-catalyzed enantioselective β-C(sp³)H arylation, alkenylation, and alkynylation. This mono-protected aminomethyl oxazoline (MPAO) ligand was used in the challenging desymmetrization of isopropyl groups.

기타 정보

Formation of α-chiral centers by asymmetric β-C(sp³)–H arylation, alkenylation, and alkynylation

안전성 정보

• 유해 및 위험 성명서: H413
• Hazard Classifications: Aquatic Chronic 4
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable