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Merck
모든 사진(1)

주요 문서

900624

Sigma-Aldrich

Di-t-butyl oxaziridine

≥95%

동의어(들):

Kurti oxaziridine

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About This Item

실험식(Hill 표기법):
C9H19NO
CAS Number:
Molecular Weight:
157.25
MDL number:
UNSPSC 코드:
12352000
NACRES:
NA.22
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Quality Level

분석

≥95%

양식

liquid

재고 정보

available only in USA

refractive index

n/D 1.4453

density

0.90 g/mL

저장 온도

2-8°C

SMILES string

CC(C)(C)C1(NO1)C(C)(C)C

InChI

1S/C9H19NO/c1-7(2,3)9(10-11-9)8(4,5)6/h10H,1-6H3

InChI key

BEGIYSAPGHHUSW-UHFFFAOYSA-N

애플리케이션

This oxaziridine has been used in synthetic methods for amination, heteroatom transfer, and C-H functionalization. Recently, the lab of Laszlo Kurti demonstrated its application for direct electrophilic primary and secondary amination of arylmetals in the presence of Cu(I) salts -- void of precious metal catalysts, ligands, protecting groups, or directing groups.

픽토그램

Flame

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Self-react. C

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 3

Flash Point (°F)

143.6 °F

Flash Point (°C)

62 °C


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Zhe Zhou et al.
Journal of the American Chemical Society, 139(1), 115-118 (2016-12-23)
Herein we disclose a novel method for the facile transfer of primary (-NH2) and secondary amino groups (-NHR) to heteroaryl- as well as arylcuprates at low temperature without the need for precious metal catalysts, ligands, excess reagents, protecting and/or directing
Yan Xu et al.
Nature chemistry, 7(10), 829-834 (2015-09-24)
Site-selective C-H functionalization has emerged as an attractive tool for derivatizing complex synthetic intermediates, but its use for late-stage diversification is limited by the functional groups that can be introduced, especially at unactivated sp(3)-hybridized positions. To overcome this, we introduce
Hongyin Gao et al.
Nature chemistry, 9(7), 681-688 (2017-06-24)
Arylmetals are highly valuable carbon nucleophiles that are readily and inexpensively prepared from aryl halides or arenes and widely used on both laboratory and industrial scales to react directly with a wide range of electrophiles. Although C-C bond formation has
Synthesis of Alkoxylamines by Alkoxide Amination with 3,3'-Di-tert-butyloxaziridine.
Ingrid C. Choong et al.
The Journal of organic chemistry, 64(18), 6528-6529 (2001-10-25)

관련 콘텐츠

Amines and their derivatives are ubiquitous substances since they make up the overwhelming majority of drug molecules, agrochemicals as well as many compounds that are produced by plants and living organisms (i.e., natural products).

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