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Merck
모든 사진(2)

주요 문서

모든 문서 보기

900278

Sigma-Aldrich

AdCyBrettPhos

동의어(들):

2-(Adamantylcyclohexylphosphino)-2’,4’,6’-triisopropyl-3,6-dimethoxybiphenyl, Cyclohexyl adamantyl(2’,4’,6’-triisopropyl-3,6-dimethoxybiphenyl-2-yl)phosphine

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크기 선택

250 MG
₩433,608
1 G
₩1,647,650

₩433,608

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청
모든 사진(2)

크기 선택

보기 변경
250 MG
₩433,608
1 G
₩1,647,650

About This Item

실험식(Hill 표기법):
C39H57O2P
CAS Number:
2197989-24-3
Molecular Weight:
588.84
UNSPSC 코드:
12352128
NACRES:
NA.22

₩433,608

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청

양식

powder

Quality Level

100

반응 적합성

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand

mp

221-224 °C

작용기

phosphine

SMILES string

O(C1=CC=C(OC)C(=C1C=2C(=CC(=CC2C(C)C)C(C)C)C(C)C)P(C3CCCCC3)C45CC6CC(CC(C6)C4)C5)C

InChI

InChI=1S/C39H57O2P/c1-24(2)30-19-32(25(3)4)36(33(20-30)26(5)6)37-34(40-7)14-15-35(41-8)38(37)42(31-12-10-9-11-13-31)39-21-27-16-28(22-39)18-29(17-27)23-39/h14-15,19-20,24-29,31H,9-13,16-18,21-23H2,1-8H3

InChI key

AMESLWUOCNKBCL-UHFFFAOYSA-N

관련 카테고리

애플리케이션

AdCyBrettPhos can be used as a ligand in the Pd-catalyzed cross-coupling reactions[1][2].

유해 및 위험 성명서

H413

예방조치 성명서

P273 - P501

Hazard Classifications

Aquatic Chronic 4

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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시험 성적서(COA)

Lot/Batch Number
MKCX0346
MKCW0745
MKCV9135
MKCQ6704
MKCQ2702

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문서 라이브러리 방문

이미 열람한 고객

Slide 1 of 1

1 of 1

BrettPhos Pd G3 98%

Sigma-Aldrich

761605

BrettPhos Pd G3

Hong Zhang et al.
Organic letters, 20(6), 1580-1583 (2018-02-24)
Two catalyst systems are described, which together provide mild and general conditions for the Pd-catalyzed C-O cross-coupling of primary alcohols. For activated substrates, such as electron-deficient aryl halides, the commercially available ligand L2 promotes efficient coupling for a variety of
Ryan P King et al.
Organic letters, 23(20), 7927-7932 (2021-10-07)
The utilization of isolated Palladium Oxidative Addition Complexes (OACs) has had a significant impact on Pd-catalyzed and Pd-mediated cross-coupling reactions. Despite their importance, widespread utility of OACs has been limited by the instability of their precursor complexes. Herein, we report

관련 콘텐츠

Buchwald Group – Professor Product Portal

The Buchwald group has developed a series of highly active and versatile palladium precatalysts and biarylphosphine ligands used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The ligands are electron-rich, and highly tunable to provide catalyst systems with a diverse scope, high stability and reactivity. Furthermore, the new series of precatalysts are air-, moisture and thermally-stable and display good solubility in common organic solvents. The use of precatalysts ensures the efficient generation of the active catalytic species and allows one to accurately adjust the ligand:palladium ratio. The ligands, precatalysts and methodology developed in the Buchwald group are user friendly and have rendered previously difficult cross couplings reactions, much easier to achieve.

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