모든 사진(1)
About This Item
Linear Formula:
Ti[OCH(CH3)2]4
CAS Number:
Molecular Weight:
284.22
Beilstein:
3679474
EC Number:
MDL number:
UNSPSC 코드:
12352106
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
분석
≥97.0%
양식
liquid
반응 적합성
core: titanium
reagent type: Lewis acid
reagent type: catalyst
refractive index
n20/D 1.464 (lit.)
bp
232 °C (lit.)
mp
14-17 °C (lit.)
density
0.96 g/mL at 20 °C (lit.)
SMILES string
CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C
InChI
1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4
InChI key
VXUYXOFXAQZZMF-UHFFFAOYSA-N
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일반 설명
Titanium(IV) isopropoxide is a Lewis acid catalyst used in organic reactions like Sharpless epoxidation.
애플리케이션
Novel metal oxide/phosphonate hybrids were formed from titanium(IV) isopropoxide in a two-step sol-gel process. Starting material for barium-strontium-titanate thin films. Used to make porous titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes. Applied in the formation of a heterosupermolecule consisting of a TiO2 nanocrystallite-viologen electron acceptor complex whose light-induced electron transfer has been demonstrated.
주의사항
may discolor on storage
기타 정보
Additive used in the Sharpless asymmetric epoxidation of allylic alcohols; Catalyst used for transesterifications with various alcohols under neutral conditions
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3
표적 기관
Central nervous system
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point (°F)
105.8 °F - Pensky-Martens closed cup
Flash Point (°C)
41 °C - Pensky-Martens closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
이미 열람한 고객
R. Imwinkelried et al.
Organic Syntheses, 65, 230-230 (1987)
Catalyst design for alkene epoxidation by molecular analogues of heterogeneous titanium-silicalite catalysts
Sole DA, et al.
ACS Catalysis, 10, 4737-4750 (2020)
Alexander V Agafonov et al.
Polymers, 12(9) (2020-09-24)
Electrorheological elastomers based on polydimethylsiloxane filled with hydrated titanium dioxide with a particle size of 100-200 nm were obtained by polymerization of the elastomeric matrix, either in the presence, or in the absence, of an external electric field. The viscoelastic
Tadashi Kokubo et al.
Journal of materials science. Materials in medicine, 19(2), 695-702 (2007-07-11)
A rectangular specimen of polyethylene terephthalate (PET) was soaked in a titania solution composed of titanium isopropoxide, water, ethanol and nitric acid at 25 degrees C for 1 h. An amorphous titanium oxide was formed uniformly on the surface of
Yann Sarazin et al.
Dalton transactions (Cambridge, England : 2003), (2)(2), 340-350 (2005-12-21)
The reactions of the bulky amino-bis(phenol) ligand Me(2)NCH(2)CH(2)N[CH(2)-3,5-Bu(t)(2)-C(6)H(2)OH-2](2)(1-H(2)) with Zn[N(SiMe(3))(2)](2)(4), [Mg[N(SiMe(3))(2)](2)](2)(5) and Ca[N(SiMe(3))(2)](2)(THF)(2)(6) yield the complexes 1-Zn, 1-Mg and 1-Ca in good yields. The X-ray structure of 1-Ca showed the complex to be dimeric, with calcium in a distorted octahedral
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