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Merck
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주요 문서

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857300

Sigma-Aldrich

(1R)-(+)-Camphor

98%

동의어(들):

(+)-Camphor, (1R)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one

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크기 선택

5 G
₩31,059
100 G
₩105,865

₩31,059

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청
모든 사진(3)

크기 선택

보기 변경
5 G
₩31,059
100 G
₩105,865

About This Item

실험식(Hill 표기법):
C10H16O
CAS Number:
464-49-3
Molecular Weight:
152.23
Beilstein:
2042745
EC Number:
207-355-2
MDL number:
MFCD00064149
UNSPSC 코드:
12352115
PubChem Substance ID:
24888438
NACRES:
NA.22

₩31,059

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청

vapor density

5.24 (vs air)

vapor pressure

4 mmHg ( 70 °C)

분석

98%

양식

powder

광학 활성

[α]25/D +44.1°, c = 10 in ethanol

autoignition temp.

870 °F

expl. lim.

3.5 %

mp

179-181 °C (lit.)

작용기

ketone

SMILES string

C[C@@]1(CC2)C(C)(C)[C@H]2CC1=O

InChI

1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m1/s1

InChI key

DSSYKIVIOFKYAU-XCBNKYQSSA-N

관련 카테고리

애플리케이션

(1R)-(+)-Camphor has been used as a standard during the enantioselective gas chromatography-mass spectrometry (GC-MS) analysis of the constituents of Achillea ligustica essential oil.[1]
It may also be used to synthesize:
  • {N,N′-bis[(1R,2R,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]-1,2-ethanediamine}, a C2-symmetrical diamine[2]
  • chiral oxazaborolidines[3]
  • (-)-(1R,2R)-1,2-dihydroxy-3,3-dimethylnorbornane[4]
Chiral intermediate[5] and auxiliary.[6][7]

애플리케이션

제품 번호
설명
가격

신호어

Danger

유해 및 위험 성명서

H228,H315,H318,H332,H371

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 2 Inhalation

표적 기관

Lungs

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 1

Flash Point (°F)

147.2 °F - closed cup

Flash Point (°C)

64 °C - closed cup

개인 보호 장비

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number
0000429626
0000429626
MKCV9875
0000241653
MKCT5496

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문서 라이브러리 방문

이미 열람한 고객

Slide 1 of 2

1 of 2

Buclizine dihydrochloride ≥98% (HPLC)

Sigma-Aldrich

SML1591

Buclizine dihydrochloride

(±)-Camphor purum, synthetic, ≥95.0% (GC)

Sigma-Aldrich

21310

(±)-Camphor

Synthetic Communications, 23, 437-437 (1993)
Synthesis of C 2-symmetrical diamine based on (1R)-(+)-camphor and application to oxidative aryl coupling of naphthols.
Caselli A, et al.
Tetrahedron Asymmetry, 14(11), 1451-1454 (2003)
The Journal of Organic Chemistry, 56, 1185-1185 (1991)
Synthesis of homochiral 1, 2-diols from (-)-fenchone and (+)-camphor.
Martinez AG, et al.
Tetrahedron Asymmetry, 5(7), 1373-1376 (1994)
Asymmetric reduction of prochiral ketones using in situ generated oxazaborolidines derived from amino alcohols of (1R)-camphor as catalysts.
Santhi V and Rao JM
Tetrahedron Asymmetry, 11(17), 3553-3560 (2000)
모든 관련된 서류 보기

Chromatograms

suitable for GC

질문

1–2 / 2 질문  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 답변

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 답변

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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