805041

2-(trimethylsilyl)-2-cyclohexen-1-one

• 실험식(Hill 표기법): C₉H₁₆OSi
• CAS Number: 72162-99-3
• Molecular Weight: 168.31
• MDL number: MFCD11502410
• UNSPSC 코드: 12352100
• PubChem Substance ID: 329768917
• NACRES: NA.22

속성

• 설명: Fp: 15.8°F
• Quality Level: 100
• 형태: liquid
• refractive index: n20/D 1.4524
• density: 0.8680 g/mL at 25 °C
• 작용기: ketone
• 저장 온도: −20°C
• SMILES string: O=C1C([Si](C)(C)C)=CCCC1
• InChI: 1S/C9H16OSi/c1-11(2,3)9-7-5-4-6-8(9)10/h7H,4-6H2,1-3H3
• InChI key: SXGCQSJRVVKTOH-UHFFFAOYSA-N

설명

일반 설명

2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.

애플리케이션

The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.

기타 정보

Cycloadditions of Cyclohexynes and Cyclopentyne

Modular synthesis of the pentacyclic core of batrachotoxin and select batrachotoxin analogue designs

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H228,H302
• 예방조치 성명서: P210 - P301 + P312 + P330 - P370 + P378
• Hazard Classifications: Acute Tox. 4 Oral - Flam. Sol. 2
• Storage Class Code: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flash Point (°F): 15.8 °F
• Flash Point (°C): -9 °C