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Merck
모든 사진(2)

문서

734624

Sigma-Aldrich

Cerium(IV) oxide-samarium doped

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<0.5 μm particle size, powder, contains 20 mol % samarium as dopant

동의어(들):

SDC-20, SDC, Samarium-doped ceria

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About This Item

실험식(Hill 표기법):
CeO2
Molecular Weight:
172.11
MDL number:
UNSPSC 코드:
26111700
PubChem Substance ID:
NACRES:
NA.23

형태

powder

포함

20 mol % samarium as dopant

구성

Sm0.2Ce0.8O1.9

환경친화적 대안 제품 특성

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

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표면적

10-14 m2/g

입자 크기

0.1-0.5 μm (d50)
<0.5 μm

벌크 밀도

1.787 g/mL

환경친화적 대안 카테고리

SMILES string

[Sm].O=[Ce]=O

InChI

1S/Ce.2O.Sm

InChI key

AQGZISMLQKBRRO-UHFFFAOYSA-N

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일반 설명

Cerium(IV) oxide-samarium doped powder (20% mol samarium doped) (SDC-20) is an electrolytic material with a high oxygen ion conductivity. Samarium ion acts as an aliovalent cation that can be incorporated into the host lattice to increase the oxygen vacancy concentration and improve the oxide ion conduction in cerium oxide. It can be synthesized by reverse strike co-precipitation technique.
Samarium doped ceria may be used as an electrolyte in solid oxide fuel cells (SOFCs). Electrical conductivity as a function of temperature of doped ceria was investigated in a study. Relation of dopant type, oxygen vacancy ordering and ionic conductivity was investigated by transmission electron microscopy and electron energy loss spectroscopy.
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애플리케이션

Cerium(IV) oxide-samarium doped can be used in the fabrication of solid oxide fuel cells (SOFCs), which can further be used as environmentally-friendly sources of alternative energy.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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문서 라이브러리 방문

Hugo J Avila-Paredes et al.
Physical chemistry chemical physics : PCCP, 11(38), 8580-8585 (2009-09-24)
We report a correlation between oxygen ionic conductivity and the enthalpy of formation of trivalent-doped ceria from the component binary oxides observed at relatively low temperatures (150-275 degrees C). The bulk conductivities of La-doped ceria samples identical to those previously
Stephan Immenschuh et al.
Transplantation, 99(1), 56-62 (2014-08-15)
Treatment of patients with antibody-mediated rejection (AMR) after kidney transplantation by rituximab and plasmapheresis is ambiguous. Because of its unknown efficiency and serious side effects, biomarkers, which are predictive for responsiveness to this treatment in AMR patients, are required. Twenty
Intermediate-temperature electrochemical performance of a polycrystalline PrBaCo2O5+ δ cathode on samarium-doped ceria electrolyte.
Chen D, et al.
Journal of Power Sources, 188(1), 96-105 (2009)
Oxygen vacancy ordering in heavily rare-earth-doped ceria.
Ou DR, et al.
Applied Physics Letters, 89(17) (2006)
Jun Zhang et al.
Scientific reports, 4, 7082-7082 (2014-11-19)
In this work, redox-active Mn or Cr is introduced to the B site of redox stable perovskite Sr(0.95)Ti(0.9)Nb(0.1)O3.00 to create oxygen vacancies in situ after reduction for high-temperature CO2 electrolysis. Combined analysis using X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron

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