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Merck
모든 사진(3)

주요 문서

238538

Sigma-Aldrich

Cerium(III) nitrate hexahydrate

99% trace metals basis

동의어(들):

Cerium trinitrate, Cerous nitrate hexahydrate, Nitric acid cerium salt

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About This Item

Linear Formula:
Ce(NO3)3 · 6H2O
CAS Number:
Molecular Weight:
434.22
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.23
분석:
99% trace metals basis
양식:
crystals and lumps

Quality Level

분석

99% trace metals basis

양식

crystals and lumps

반응 적합성

reagent type: catalyst
core: cerium

불순물

1-2% La

SMILES string

[Ce+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;

InChI key

QQZMWMKOWKGPQY-UHFFFAOYSA-N

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일반 설명

Cerium (III) nitrate hexahydrate is the most common form of cerium nitrate. It is a white-to-yellow crystalline salt, and it is highly soluble in water, alcohol, and acetone, although solutions can appear slightly hazy. Like many trivalent metal nitrates, cerium (III) nitrate hexahydrate has a low-melting point of only 57 °C and thermally decomposes at low temperatures too, beginning at 190 °C and proceeding rapidly at 280 °C with complete decomposition at 390-400 °C.

애플리케이션

Cerium (III) nitrate hexahydrate is widely used as a source of cerium, especially in the synthesis of micro- or nano-structured ceria (cerium oxide). Because of its high solubility and low decomposition temperature, cerium (III) nitrate hexahydrate is an ideal reagent for hydrothermal reactions, sol-gel processing, and co-precipitation and calcination reactions.

Ceria is one of the best studied materials-platforms for catalysis and solid oxide fuel cells. Consequently scientists have developed well-controlled synthetic protocols using cerium (III) nitrate hexahydrate for preparing ceria nanoparticles including nano cubes, nanotubes, and nanorods. The tailorable synthesis facilitates using ceria as a catalyst support, for example leveraging the porosity of the microstructure to impregnate metals and metal alloys, or for example synthesizing ceria-based materials like ceria-zirconia.

픽토그램

CorrosionEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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문서 라이브러리 방문

Kenji Kaneko et al.
Nano letters, 7(2), 421-425 (2007-02-15)
Colloidal cerium oxide (CeO2) nanocrystals prepared by hydrothermal synthesis were characterized by high-resolution transmission electron microscopy (HRTEM) and three-dimensional electron tomography (3D-ET). HRTEM images of individual CeO2 nanocrystals were then simulated by Blochwave and multislice simulations to determine the atomic
Wei-Qiang Han et al.
Journal of the American Chemical Society, 127(37), 12814-12815 (2005-09-15)
Well-crystalline CeO(2-x) nanotubes are synthesized via a mild hydrothermal reaction route using cerium nitrate and ammonium hydroxide as reactants. The CeO(2-x) nanotubes have the same structure as the bulk CeO2 but larger lattice parameter. The measurement of the ratio of
Microwave assisted preparation of cerium dioxide nanocubes
Tao Y, et al
Materials Chemistry and Physics, 112(3), 973-976 (2008)
Formation mechanism of nanocrystalline ceria in aqueous solutions of cerium(III) nitrate and hexamethylenetetramine
Polezhaeva OS, et al
Inorganic Materials, 44(10, 51-557 (2008)
Boosting CO2 hydrogenation via size-dependent metal?support interactions in cobalt/ceria-based catalysts.
Parastaev A, et al.
Nature catalysis, 3, 526?533 -526?533 (2020)

문서

Rare earth elements are vital in everyday life worldwide: catalysts in cars, colors in screens, magnets in electronics. Essential for modern living.

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