732737

4-(Benzaldehyde diethylacetal)magnesium bromide solution

1 M in THF

• 동의어(들): 4-(Diethoxymethyl)phenylmagnesium bromide
• 실험식(Hill 표기법): C₁₁H₁₅BrMgO₂
• Molecular Weight: 283.44
• MDL number: MFCD11553216
• UNSPSC 코드: 12352103
• PubChem Substance ID: 329764754
• NACRES: NA.22

속성

• 양식: solution
• 반응 적합성: reaction type: Grignard Reaction
• 농도: 1 M in THF
• density: 1.013 g/mL at 25 °C
• 작용기: ether
• SMILES string: CCOC(OCC)c1ccc([Mg]Br)cc1
• InChI: 1S/C11H15O2.BrH.Mg/c1-3-12-11(13-4-2)10-8-6-5-7-9-10;;/h6-9,11H,3-4H2,1-2H3;1H;/q;;+1/p-1
• InChI key: APPJPCOJOCVSMA-UHFFFAOYSA-M

설명

애플리케이션

4-(Benzaldehyde diethylacetal)magnesium bromide can be used as a substrate in the sp³ C-H arylation of tetrahydroisoquinolines using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ).[1]

안전성 정보

• 픽토그램: GHS02,GHS08,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H314,H335,H336,H351
• 예방조치 성명서: P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1C - STOT SE 3
• 표적 기관: Respiratory system
• 보충제 위험성: EUH014,EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): -22.0 °F
• Flash Point (°C): -30 °C