717460

Chloro[tri(o-tolyl)phosphine]gold(I)

95%

• 동의어(들): [Tri(2-methylphenyl)phosphine]gold(I) chloride
• 실험식(Hill 표기법): C₂₁H₂₁AuClP
• CAS Number: 83076-07-7
• Molecular Weight: 536.78
• MDL number: MFCD14155882
• UNSPSC 코드: 12352300
• PubChem Substance ID: 329763492

속성

• 분석: 95%
• 양식: solid
• 반응 적합성: core: gold; reagent type: catalyst
• SMILES string: Cl[Au].Cc1ccccc1P(c2ccccc2C)c3ccccc3C
• InChI: 1S/C21H21P.Au.ClH/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;/h4-15H,1-3H3;;1H/q;+1;/p-1
• InChI key: VECXLHSTZNCQLD-UHFFFAOYSA-M

설명

애플리케이션

Gold Catalysts — 21st Century ′Gold Rush′

Catalyst for:

• Alkylation of silyl enol ethers with orthoalkynylbenzoic acid esters
• Cycloisomerization
• Cyclization of 1,6-enynes
• Tandem [3,3]-sigmatropic rearrangement-cycloisomerization cascade
• Cycloaddition of enyne derivatives with aryl alkynes or alkenes

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable