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Merck
모든 사진(1)

문서

689092

Sigma-Aldrich

Isopropyl acetoacetate

Arxada quality, ≥99.0% (GC)

로그인조직 및 계약 가격 보기


About This Item

Linear Formula:
CH3COCH2COOCH(CH3)2
CAS Number:
Molecular Weight:
144.17
Beilstein:
1757046
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

분석

≥99.0% (GC)

형태

liquid

품질

Arxada quality

제조업체/상표

Arxada AG

불순물

≤0.10% acid (as acetic acid)
≤0.10% water
≤0.5% ethyl acetoacetate

bp

95 °C/52 hPa (lit.)

density

0.989 g/mL at 20 °C (lit.)

SMILES string

CC(C)OC(=O)CC(C)=O

InChI

1S/C7H12O3/c1-5(2)10-7(9)4-6(3)8/h5H,4H2,1-3H3

InChI key

GVIIRWAJDFKJMJ-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

Isopropyl acetoacetate can be used as a reactant to synthesize:
  • Isopropyl 2-acetyl-3-phenyl-2-propenoate via Knoevenagel reaction in the presence of Ti(O-i-Pr)4.
  • Substituted 1,4-dihydropyridines by reacting with cinnamaldehydes and primary amines.
  • 5-Isopropoxycarbonyl-6-methyl-4-phenyl-3,4-dihydropyrimidin-2(1H)-thione via Biginelli reaction with benzaldehyde and thiourea.

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Skin Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point (°F)

159.8 °F - closed cup

Flash Point (°C)

71 °C - closed cup

개인 보호 장비

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


시험 성적서(COA)

제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.

이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-dicarbonyl compounds: straightforward access to enantiomerically enriched dihydropyridines
Jiang J, et al.
Angewandte Chemie (International Edition in English), 47(13), 2458-2462 (2008)
Novel Knoevenagel-type reaction via titanium enolate derived from Ti(Oi-Pr)4 and diketene
Hayashi M, et al.
Tetrahedron, 60(32), 6777-6783 (2004)
Synthesis and biological evaluation of novel isopropyl 2-thiazolopyrimidine-6-carboxylate derivatives
Kotaiah Y, et al.
J. Korean Chem. Soc., 56(1), 68-73 (2012)
M M V Ramana et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 152, 165-171 (2015-07-25)
In the present work, isopropyl-6-amino-4-(3,5-bis(trifluoromethyl)phenyl)-5-cyano-2-methyl-4H-pyran-3-carboxylate (4H-pyran analog) has been synthesized by a three component reaction catalyzed by CsOH/γ-Al2O3 and characterized. The interaction of 4H-pyran analog with herring sperm DNA (hs DNA) under physiological conditions (phosphate buffer of pH 7.2) was

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