682314
(S)-N-Methyl-N-diphenylphosphino-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine
동의어(들):
(1S)-1-(Diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene, Methyl-BoPhoz
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모든 사진(1)
About This Item
실험식(Hill 표기법):
C37H35FeNP2
CAS Number:
Molecular Weight:
611.47
MDL number:
UNSPSC 코드:
12352005
PubChem Substance ID:
추천 제품
![(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ≥97%](/deepweb/assets/sigmaaldrich/product/structures/245/493/2ae2dd8a-65cc-4aba-9a1f-1292eb1ad8e0/640/2ae2dd8a-65cc-4aba-9a1f-1292eb1ad8e0.png)
![(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ≥97%](/deepweb/assets/sigmaaldrich/product/structures/168/768/54a48841-6fe6-437a-81af-8c2e54117ef3/640/54a48841-6fe6-437a-81af-8c2e54117ef3.png)
![(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine ≥96%](/deepweb/assets/sigmaaldrich/product/structures/418/090/c80a189a-0e74-4983-bf17-13d1f9e5358b/640/c80a189a-0e74-4983-bf17-13d1f9e5358b.png)
![(SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97%](/deepweb/assets/sigmaaldrich/product/structures/139/971/7e978306-0437-46d8-9486-ea1a19ff3a47/640/7e978306-0437-46d8-9486-ea1a19ff3a47.png)
![(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine ≥97%](/deepweb/assets/sigmaaldrich/product/structures/809/974/e027b628-7c2e-4bde-be7e-f9298d0c8b04/640/e027b628-7c2e-4bde-be7e-f9298d0c8b04.png)
양식
solid
mp
104.1-109.2 °C
작용기
amine
phosphine
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6
InChI
1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1
InChI key
ZIAZHUWEJYUGEO-FBHGDYMESA-N
애플리케이션
Methyl-BoPhoz can be used:
- As an efficient ligand for asymmetric hydrogenation reactions.[1][2]
- To synthesize a single enantiomer of cyclopropylalanine via hydrogenation reaction using rhodium catalyst.[2]
- To prepare chiral phenylalanine derivatives from α-amido cinnamic acids (or esters) using rhodium catalyst.[3]
법적 정보
Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US6590115 and any patents arising therefrom apply.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
가장 최신 버전 중 하나를 선택하세요:
Enantioselective Access to Chiral Drugs by using Asymmetric Hydrogenation Catalyzed by Rh (P-OP) Complexes
Etayo P, et al.
Chemistry?A European Journal , 17(50), 13978-13982 (2011)
Protecting-group-free synthesis of a dual CCK1/CCK2 receptor antagonist
Liu J, et al.
Organic & Biomolecular Chemistry, 9(8), 2654-2660 (2011)
The preparation of enantiomerically pure cyclopropylalanine.
Boaz NW, et al.
Tetrahedron Asymmetry, 14(22), 3575-3580 (2003)
문서
P-Phos ligand family enhances catalysis, featuring atropisomeric biaryl bisphosphine with unique structural elements.
활성 필터
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
고객지원팀으로 연락바랍니다.
