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Merck
모든 사진(1)

주요 문서

666025

Sigma-Aldrich

13,6-N-Sulfinylacetamidopentacene

97%

동의어(들):

16-Acetyl-6,13-dihydro-15-oxide -13,6-(epithioimino)pentacene, NSFAAP, soluble pentacene precursor

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About This Item

실험식(Hill 표기법):
C24H17NO2S
CAS Number:
Molecular Weight:
383.46
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.23

분석

97%

양식

solid

mp

169-190 °C

solubility

THF: soluble
dioxane: soluble
methylene chloride: soluble

형광

λex 251 nm; λem 498 nm in chloroform

저장 온도

−20°C

SMILES string

CC(=O)N1[C@@H]2c3cc4ccccc4cc3[C@@H](c5cc6ccccc6cc25)S1=O

InChI

1S/C24H17NO2S/c1-14(26)25-23-19-10-15-6-2-4-8-17(15)12-21(19)24(28(25)27)22-13-18-9-5-3-7-16(18)11-20(22)23/h2-13,23-24H,1H3/t23-,24+,28?

InChI key

HIABOOSIYBUBKB-XUEDKKMFSA-N

일반 설명

13,6-N-Sulfinylacetamidopentacene (NSFAAP) is a highly soluble pentacene precursor that can be synthesized by Lewis acid-catalyzed Diels-Alder reaction of pentacene and N-sulfinylacetamide. It can be spin coated to form an organic thin film which can be used in organic electronics.[1]

애플리케이션

NSFAAP can be used as a conjugating polymer that can be used in designing of thin film transistors with field mobility of 0.27 cm2V-1s-1 and a threshold voltage parameter of -4.25 V.[1][2][3][4]

제조 메모

Dried thin films convert to pentacene at 150-200 °C

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves


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문서 라이브러리 방문

High-performance, solution-processed organic thin film transistors from a novel pentacene precursor
Afzali A, et al.
Journal of the American Chemical Society, 124(30), 8812-8813 (2002)
On-Demand Patterning of Nanostructured Pentacene Transistors by Scanning Thermal Lithography
Shaw JE
Advanced Materials, 25(4), 552-558 (2013)
An organic thin film transistor based non-volatile memory with zinc oxide nanoparticles
Lee WK, et al.
Thin Solid Films, 519(15), 5208-5211 (2011)
Enhanced thin-film transistor performance by combining 13, 6-N-sulfinylacetamidopentacene with printed PEDOT: PSS electrodes
Luzio A, et al.
Chemistry of Materials, 23(4), 1061-1069 (2011)
Ali Afzali et al.
Journal of the American Chemical Society, 124(30), 8812-8813 (2002-07-26)
The Lewis acid-catalyzed Diels-Alder reaction of the organic semiconductor pentacene with N-sulfinylacetamide yields a soluble adduct. Spin-coated thin films of this adduct undergo solid-phase conversion to form thin films of pentacene at moderate temperatures. Organic thin film transistors fabricated by

문서

Silylethyne substitution offers an opportunity to tune solubility for application-specific needs and self-assembly for electronic performance and has yielded semiconductors with excellent device performance.

Fabrication procedure of organic field effect transistor device using a soluble pentacene precursor.

질문

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