656763

Di-μ-chlorotetraethylene dirhodium(I)

• 동의어(들): Bis[chlorobis(ethylene)rhodium], Bis[chlorodiethylenerhodium], Chlorobis(ethylene)rhodium dimer, Dichlorotetra(ethene)dirhodium, Dichlorotetrakis(ethene)dirhodium, Diethylenerhodium chloride dimer, Divinylrhodium chloride dimer, Tetrakis(ethylene)dichlorodirhodium, [Rh(C₂H₄)₂Cl]₂
• 실험식(Hill 표기법): C₈H₁₆Cl₂Rh₂
• CAS Number: 12081-16-2
• Molecular Weight: 388.93
• EC Number: 235-145-0
• MDL number: MFCD00013206
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24884230
• NACRES: NA.22

속성

• 양식: solid
• Quality Level: 100
• 반응 적합성: core: rhodium; reagent type: catalyst
• 저장 온도: −20°C
• SMILES string: Cl[Rh].Cl[Rh].C=C.C=C.C=C.C=C
• InChI: 1S/4C2H4.2ClH.2Rh/c4*1-2;;;;/h4*1-2H2;2*1H;;/q;;;;;;2*+1/p-2
• InChI key: OOQJCPOXJFCGCR-UHFFFAOYSA-L

설명

애플리케이션

Di-μ-chlorotetraethylene dirhodium(I) may be used in the preparation of Π-bound rhodium organometallic complexes of ROMP-derived poly(1,5-cyclooctadiene) (poly(COD)). [ROMP= Ring-Opening Metathesis Polymerization; COD= 1,5-cyclooctadiene][1]

Precursor to Rh(I) norbornadiene catalyst used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones.[2]

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H319
• 예방조치 성명서: P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)