65671
(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine
≥97%
동의어(들):
(1S)-1-[(1R)-1-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene, Walphos SL-W001-2
로그인조직 및 계약 가격 보기
크기 선택
100 MG
₩130,326
500 MG
₩551,957
5 G
₩3,872,124
50 G
₩27,796,080
100 G
₩32,247,667
모든 사진(1)
크기 선택
보기 변경
100 MG
₩130,326
500 MG
₩551,957
5 G
₩3,872,124
50 G
₩27,796,080
100 G
₩32,247,667
About This Item
실험식(Hill 표기법):
C46H32F12FeP2
CAS Number:
Molecular Weight:
930.52
MDL number:
UNSPSC 코드:
12352101
PubChem Substance ID:
NACRES:
NA.22
추천 제품
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분석
≥97%
광학 순도
ee: ≥99%
작용기
fluoro
phosphine
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F
InChI
1S/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m0../s1
InChI key
LKNKYBWIZNAXBY-WLOLSGMKSA-N
일반 설명
The product is an air-stable and non-hygroscopic Solvias chiral phosphine ligand.
애플리케이션
Walphos SL-W001-2, in the presence of a ruthenium catalyst may be used as a ligand in the following processes:
포장
Bottomless glass bottle. Contents are inside inserted fused cone.
기타 정보
sold in collaboration with Solvias AG
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
Enantioselective Rh (I)-catalyzed addition of arylboronic acids to cyclic ketimines.
Kong J, et al.
Organic Letters, 17(22), 5520-5523 (2015)
Afrooz Zirakzadeh et al.
Organometallics, 33(8), 1945-1952 (2014-05-06)
Two representative Walphos analogues with an achiral 2,2″-biferrocenediyl backbone were synthesized. These diphosphine ligands were tested in the rhodium-catalyzed asymmetric hydrogenation of several alkenes and in the ruthenium-catalyzed hydrogenation of two ketones. The results were compared with those previously obtained
활성 필터
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
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