559830
Methyl-2-benzoylbenzoate
97%
동의어(들):
2-Benzoylbenzoic acid methyl ester, Methyl o-benzoylbenzoate, o-(Methoxycarbonyl)benzophenone
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모든 사진(1)
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25 G
₩106,372
About This Item
Linear Formula:
C6H5COC6H4CO2CH3
CAS Number:
Molecular Weight:
240.25
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
분석
97%
양식
solid
mp
48-53 °C (lit.)
작용기
ester
ketone
phenyl
SMILES string
COC(=O)c1ccccc1C(=O)c2ccccc2
InChI
1S/C15H12O3/c1-18-15(17)13-10-6-5-9-12(13)14(16)11-7-3-2-4-8-11/h2-10H,1H3
InChI key
NQSMEZJWJJVYOI-UHFFFAOYSA-N
일반 설명
Methyl-2-benzoylbenzoate is a 2-acylarylcarboxylate.
- It can undergo asymmetric transfer hydrogenation reaction in propanol in the presence of a Ruthenium catalyst.[1]
- Methyl-2-benzoylbenzoate is formed as one of the reaction products during the reaction between methyl benzoate and lithium 2,2,6,6-tetramethylpiperidide (LiTMP) at -117°C.[2]
- Methyl-2-benzoylbenzoate can be synthesized from the reaction between corresponding 2-substituted benzoic acid and thionyl chloride in methanol.[3]
신호어
Warning
유해 및 위험 성명서
예방조치 성명서
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves
이미 열람한 고객
Dipole stabilized carbanions. Reactions of benzoate esters with lithium 2, 2, 6, 6-tetramethylpiperidide.
Upton CJ and Beak P.
The Journal of Organic Chemistry, 40(8), 1094-1098 (1975)
Stereoselective synthesis of 3-substituted phtalides via asymmetric transfer hydrogenation using well-defined ruthenium catalysts under neutral conditions.
Everaere K, et al.
Tetrahedron Letters, 42(10), 1899-1901 (2001)
One-Step Synthesis of 1-Oxo- 1,2-dihydroisoquinoline-3-carboxylic Acid Derivatives.
Nunami K, et al.
The Journal of Organic Chemistry, 44(11), 1887-1888 (1979)
Miwa Morizane et al.
Journal of toxicology and environmental health. Part A, 78(23-24), 1450-1460 (2015-12-23)
A recent in vitro study reported that the photoinitiator 2-isopropylthioxanthone (2-ITX) is an endocrine-disrupting compound (EDC). However, it is not clear whether other photoinitiators such as 1-hydroxycyclohexyl phenyl ketone (1-HCHPK) and 2-methyl-4'-(methylthio)-2-morpholinopropiophenone (MTMP) produce endocrine-disrupting effects. The purpose of this
Miguel A Lago et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 33(3), 518-529 (2016-01-21)
Since the UV ink photoinitiator (PI) isopropylthioxanthone (ITX) was discovered in packaged milk, studies of print contamination have focused primarily on PIs but have also included amine synergists. Many other substances are used or formed during the print process, yet
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