추천 제품
분석
97%
mp
77-80 °C (lit.)
SMILES string
CC(C)(C)c1cc(nc(n1)C(C)(C)C)C(C)(C)C
InChI
1S/C16H28N2/c1-14(2,3)11-10-12(15(4,5)6)18-13(17-11)16(7,8)9/h10H,1-9H3
InChI key
VYWSYEDVFVGRGG-UHFFFAOYSA-N
일반 설명
2,4,6-Tri-tert-butylpyrimidine (TTBP) is a non-hygroscopic sterically hindered base. It can be prepared by the reaction between tert-butyl methyl ketone and tert-butyronitrile.3 TTBP is a suitable alternative to 2,6-di-tert-butylated pyridines in glycosylation reactions.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
이미 열람한 고객
![[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I) 95%](/deepweb/assets/sigmaaldrich/product/structures/336/250/c96c15b3-1a1c-479f-a588-76e98905be23/640/c96c15b3-1a1c-479f-a588-76e98905be23.png)
2, 4, 6-Tri-tert-butylpyrimidine (TTBP): A cost effective, readily available alternative to the hindered base 2, 6-di-tert-butylpyridine and its 4-substituted derivatives in glycosylation and other reactions.
Crich D, et al.
Synthesis, 2001(02), 0323-0326 (2001)
On the mechanism of the reaction between ketones and trifluoromethanesulfonic anhydride. An improved and convenient method for the preparation of pyrimidines and condensed pyrimidines.
Garcia Martinez A, et al.
The Journal of Organic Chemistry, 57(5), 1627-1630 (1992)
1-Benzenesulfinyl piperidine/trifluoromethanesulfonic anhydride: a potent combination of shelf-stable reagents for the low-temperature conversion of thioglycosides to glycosyl triflates and for the formation of diverse glycosidic linkages.
Crich D and Smith M.
Journal of the American Chemical Society, 123(37), 9015-9020 (2001)
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