528218
N-Chlorophthalimide
96%
동의어(들):
2-Chloro-1H-isoindole-1,3(2H)-dione, 2-Chloro-2,3-dihydro-1H-isoindole-1,3-dione, 2-Chloroisoindole-1,3-dione, 2-Chloroisoindoline-1,3-dione, Phthalimide chloride, Phthalimidoyl chloride
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모든 사진(2)
About This Item
실험식(Hill 표기법):
C8H4ClNO2
CAS Number:
Molecular Weight:
181.58
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
추천 제품
분석
96%
mp
188-198 °C (lit.)
SMILES string
ClN1C(=O)c2ccccc2C1=O
InChI
1S/C8H4ClNO2/c9-10-7(11)5-3-1-2-4-6(5)8(10)12/h1-4H
InChI key
WDRFYIPWHMGQPN-UHFFFAOYSA-N
관련 카테고리
일반 설명
N-Chlorophthalimide in anhydrous acetic acid serves as a useful oxidizing reagent for use in various direct titrimetric analyses. N-Chlorophthalimide can be synthesized by reacting phthalimide, t-butyl hypochlorite, water and t-butyl alcohol. It participates in the synthesis of 2-amino-3-benzoyl-α-(methylthio)phenylacetamide.
애플리케이션
N-Chlorophthalimide may be employed in the synthesis of:
- α-amino acetal
- α-amino nitro compounds
- vicinal diamine
- α,β-unsaturated vicinal haloamino nitro compound
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
이미 열람한 고객
Aminochlorination reaction with N-chlorophthalimide as a new nitrogen/chlorine source resulting in a-amino derivatives.
Qian Y, et al.
Tetrahedron, 68(31), 6198-6203 (2012)
N-Chlorophthalimide as a mild and efficient chlorination reagent in the Gassman ortho alkylation of aromatic amines. Synthesis of 3-(methylthio) oxindoles.
Cybulski M, et al.
Tetrahedron Letters, 55(40), 5423-5425 (2014)
N Jayasree et al.
Talanta, 32(11), 1067-1068 (1985-11-01)
A stable new oxidimetric titrant, N-chlorophthalimide in anhydrous acetic acid, is proposed for direct titrations of a variety of simple and complex reductants such as As(III), Sb(III), Fe(II), ferrocyanide, iodide, ascorbic acid, hydroquinone, hydrazine, phenylhydrazine, benzhydrazide, isonicotinic acid hydrazide, semicarbazide
Tertiary Butyl Hypochlorite as as N-Chlorinating Agent.
Zimmer H and Audrieth LF.
Journal of the American Chemical Society, 76(14), 3856-3857 (1954)
Development and a practical synthesis of nepafenac intermediate via modified Gassman reaction.
Cybulski M, et al.
Letters in Organic Chemistry, 9(7), 461-464 (2012)
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