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Merck
모든 사진(3)

문서

417556

Sigma-Aldrich

4-Fluorophenylboronic acid

≥95%

동의어(들):

(4-Fluorophenyl)boric acid, (4-Fluorophenyl)dihydroxyborane, (4-Fluorophenyl)dihydroxyboron, (p-Fluorophenyl)boric acid, 4-Fluorobenzeneboronic acid, p-Fluorobenzylboronic acid, p-Fluorophenylboronic acid, NSC 142683

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모든 사진(3)

About This Item

Linear Formula:
FC6H4B(OH)2
CAS Number:
1765-93-1
Molecular Weight:
139.92
Beilstein:
2829653
MDL number:
MFCD00039136
UNSPSC 코드:
12352103
PubChem Substance ID:
24866160
NACRES:
NA.22

분석

≥95%

형태

powder

mp

262-265 °C (lit.)

SMILES string

OB(O)c1ccc(F)cc1

InChI

1S/C6H6BFO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H

InChI key

LBUNNMJLXWQQBY-UHFFFAOYSA-N

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관련 카테고리

애플리케이션

4-Fluorophenylboronic acid can be used as a reactant in coupling reactions with arenediazonium tetrafluoroborates, iodonium salts, and iodanes. It is also used to make novel biologically active terphenyls.

It can also be used as a reactant in:
  • Suzuki coupling using microwave and triton B catalyst.
  • Pd-catalyzed direct arylation of pyrazoles with phenylboronic acids.
  • Mizoroki-Heck and Suzuki-Miyaura coupling reactions catalyzed by palladium nanoparticles.
  • Cu-catalyzed Petasis reactions.
  • Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence.
  • Ruthenium catalyzed direct arylation.
  • Rh-catalyzed asymmetric conjugate additions.
  • Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids.
  • Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions.
  • Suzuki cross-coupling of tetrabromothiophene.
  • Palladium-catalyzed addition to nitriles.

기타 정보

Contains varying amounts of anhydride

픽토그램

Exclamation mark
GHS07

신호어

Warning

유해 및 위험 성명서

H302,H315,H319,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves

시험 성적서(COA)

제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.

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문서 라이브러리 방문

Cross-coupling of arenediazonium tetrafluoroborates with arylboronic acids catalysed by palladium
Sylvain Darses, et al.
Tetrahedron Letters, 37, 3857-3860 (1996)
Synthesis of tetraarylthiophenes by regioselective Suzuki cross-coupling reactions of tetrabromothiophene
Thanh Tuan Dang, et al.
Tetrahedron Letters, 48, 5, 845-847 (2007)
Yuvraj Satkar et al.
Frontiers in chemistry, 8, 563470-563470 (2020-11-17)
The chemoselective reaction of the C- followed by the O-centered naphthyl radicals with the more electron-deficient hypervalent bond of the diaryliodonium(III) salts is described. This discovered reactivity constitutes a new activation mode of the diaryliodonium(III) salts which enabled a one-pot
Suk-Ku Kang et al.
The Journal of organic chemistry, 61(14), 4720-4724 (1996-07-12)
The palladium-catalyzed cross-coupling reaction of iodinanes (iodonium salts and iodanes) with organoboron compounds to form carbon-carbon bonds was achieved at ambient temperature under aqueous conditions in the absence of base. Coupling of phenylboronic acid with diphenyliodonium tetrafluoroborate in the presence
Microwave-enhanced triton B catalyzed Suzuki coupling reaction
Meshram, H. M.; et al.
Indian J. Chem. B, 51, 362-365 (2012)
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