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Merck
모든 사진(2)

주요 문서

520853

Sigma-Aldrich

Potassium tetrachloroplatinate(II)

≥99.9% trace metals basis

동의어(들):

Potassium platinum(II) chloride

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크기 선택

1 G
₩334,646
5 G
₩1,216,173
25 G
₩4,277,312

₩334,646


예상 입고일2025년 1월 31일세부사항


벌크 견적 요청

크기 선택

보기 변경
1 G
₩334,646
5 G
₩1,216,173
25 G
₩4,277,312

About This Item

Linear Formula:
K2PtCl4
CAS Number:
Molecular Weight:
415.09
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.23
분석:
≥99.9% trace metals basis
양식:
powder or crystals

₩334,646


예상 입고일2025년 1월 31일세부사항


벌크 견적 요청

Quality Level

분석

≥99.9% trace metals basis

양식

powder or crystals

구성

Pt, ≥46.2%

불순물

≤1000.0 ppm Trace Metal Analysis

density

3.38 g/mL at 25 °C (lit.)

SMILES string

[K+].[K+].Cl[Pt--](Cl)(Cl)Cl

InChI

1S/4ClH.2K.Pt/h4*1H;;;/q;;;;2*+1;+2/p-4

InChI key

RVRDLMCWUILSAH-UHFFFAOYSA-J

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일반 설명

Potassium tetrachloroplatinate(II) is a crystalline solid that is insoluble in water and soluble in organic solvents. It is widely used in the field of nanomaterial synthesis, catalysis, and energy storage.[1] [2]

애플리케이션

Potassium tetrachloroplatinate(II) can be used:
  • As a precursor to prepare platinum nanoparticles and mesoporous platinum nanospheres with tunable pore sizes.[1]
  • As a catalyst for selective methane oxidation through C-H activation. In addition, to synthesize octahedral [email protected] nanocrystals with an ultrathin PtNi alloy shell. The nanocrystals exhibited better ORR activity and durability than the commercial Pt/C for fuel cells.[2]
  • To prepare Pt atomic clusters were synthesized using a one-step carbon-defect-driven electroless deposition method. These catalysts demonstrated low overpotential, high activity for the hydrogen evolution reaction, exceptional stability, and improved utilization efficiency of Pt. The Pt-AC/DG (Atomic Clusters/Defective Graphene) cathode showed excellent hydrogen production activity, remarkable stability, and significantly reduced Pt usage compared to the Pt/C catalyst.[3]
  • As a starting material to synthesize cyclometalated platinum(II) complexes with long-lived luminescence in solution.[4]

특징 및 장점

Reacts with bis(dithiolates) to form metal-bis(dithiolates) with applications in laser Q-switch materials, liquid crystals, optical CD recording media, bar code materials and superconductivity. Reacts with capping polymers to form shape-control colloidal platinum nanoparticles for catalysis and photocatalysts.

픽토그램

Skull and crossbonesHealth hazardCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Carbon-Defect-Driven Electroless Deposition of Pt Atomic Clusters for Highly Efficient Hydrogen Evolution
Qingqing Cheng, et al.
Journal of the American Chemical Society, 142, 5594-5601 (2020)
Alkyl chain functionalised, cyclometalated platinum(II) complexes: Syntheses, luminescence properties and X-ray crystal structure
Juliette A. Lowe, et al.
Journal of Organometallic Chemistry, 805, 87-93 (2016)
Selective Methane Oxidation Catalyzed by Platinum Salts in Oleum at Turnover Frequencies of Large-Scale Industrial Processes
Tobias Zimmermann, et al.
Journal of the American Chemical Society, 138, 12395-12400 (2016)
Polymeric micelle assembly for the smart synthesis of mesoporous platinum nanospheres with tunable pore sizes
Yunqi Li, et al.
Angewandte Chemie (International Edition in English), 54, 11073-11077 (2015)
Valentina Ljubomirova et al.
Analytica chimica acta, 614(2), 119-126 (2008-04-19)
A method for the separation of tetrachloroplatinate PtCl(4)(2-), and hexachloroplatinate PtCl(6)(2-), by solid-phase extraction, using a Dowex 1x10 anion exchange resin is proposed. The sequential elution and separation of PtCl(4)(2-), and PtCl(6)(2-) is achieved using selective complexing agents. The eluates

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