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Merck
모든 사진(1)

주요 문서

512079

Sigma-Aldrich

Pentafluorophenyl isocyanate

97%

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크기 선택

5 ML
₩911,064

₩911,064


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5 ML
₩911,064

About This Item

Linear Formula:
C6F5NCO
CAS Number:
Molecular Weight:
209.07
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

₩911,064


구입 가능 여부는 고객센터에 문의하십시오.

벌크 견적 요청

Quality Level

분석

97%

refractive index

n20/D 1.449 (lit.)

bp

52 °C/2 mmHg (lit.)

density

1.6 g/mL at 25 °C (lit.)

작용기

fluoro
isocyanate

저장 온도

2-8°C

SMILES string

Fc1c(F)c(F)c(N=C=O)c(F)c1F

InChI

1S/C7F5NO/c8-2-3(9)5(11)7(13-1-14)6(12)4(2)10

InChI key

QXLDBWRLZDBVGF-UHFFFAOYSA-N

일반 설명

Pentafluorophenyl isocyanate (PFPI), an aryl isocyanate, is an N-protecting reagent.[1] The photoinduced intermolecular carbamoylation of tertiary ethereal C-H bond of fused bicyclic system using PFPI/benzophenone has been reported.[2] Reacting wood polymers with PFPI can make them resistant to fungal attack by forming a stable carbamate bond.[3]

애플리케이션

Pentafluorophenyl isocyanate may be used in the preparation of:
  • pentafluorophenyl end-capped poly(ethylene glycol) (PF-PEG-PF)[4]
  • 9-O-(pentafluorophenylcarbamoyl)quinine[5]
  • 9-O-(tert-butyldimethylsilyl)-10-(pentafluorophenylcarbamoyloxy)-6′-methoxy-11-norcinchonan-9-ol[5]
  • substituted 2,6-ethynylpyridine bisphenylurea scaffolds[6]
  • novel O-xylyl bridged hexaurea receptor for atmospheric CO2 uptake[7]

픽토그램

Health hazardExclamation mark

신호어

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point (°F)

230.0 °F - closed cup

Flash Point (°C)

110 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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이미 열람한 고객

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1 of 1

NMR enantiodiscrimination by pentafluorophenylcarbamoyl derivatives of quinine: C10 versus C9 derivatization.
Uccello-Barretta G, et al.
Chirality, 23(5), 417-417 (2011)
CO2-and O2-Sensitive Fluorophenyl End-Capped Poly (ethylene glycol).
Choi JY, et al.
Macromolecular Rapid Communications, 35(1), 66-70 (2014)
Jeffrey M Engle et al.
Chemical science, 3(4), 1105-1110 (2012-04-01)
A series of sixteen bisphenylureas based on a 2,6-bis(2-anilinoethynyl)pyridine scaffold have been synthesized for use as potential anion sensors. Prior work with one of these receptors revealed a distinct fluorescence response in the presence of a suitable anion source with
Photoinduced carbamoylation of ethereal C-H bonds using pentafluorophenyl isocyanate.
Kamijo S, et al.
Tetrahedron Letters, 52(22), 2885-2888 (2011)
Fungal resistance of southern pine impregnated with methyl fluorophenyl carbamates or reacted with fluorophenyl isocyanates.
Chen GC, et al.
Wood and Fiber Science, 22(2), 165-172 (2007)

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