442003

trans-2-Butenal diethyl acetal

technical, 90%

• Linear Formula: CH₃CH=CHCH(OC₂H₅)₂
• CAS Number: 63511-92-2
• Molecular Weight: 144.21
• MDL number: MFCD00239338
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24867717
• NACRES: NA.22

속성

• grade: technical
• 분석: 90%
• refractive index: n20/D 1.412 (lit.)
• bp: 146-150 °C (lit.)
• density: 0.831 g/mL at 25 °C (lit.)
• SMILES string: [H]\C(C)=C(\[H])C(OCC)OCC
• InChI: 1S/C8H16O2/c1-4-7-8(9-5-2)10-6-3/h4,7-8H,5-6H2,1-3H3/b7-4+
• InChI key: ZUMISMXLQDKQDS-QPJJXVBHSA-N

설명

일반 설명

trans-2-Butenal diethyl acetal is an acetal. Acetals are usually derived from the aldehydes. They have two single-bonded oxygen atoms attached to the same carbon atom. They are stable under basic conditions and they can be hydrolyzed back to the carbonyl compound. Acetals serves as a carbonyl protecting group and also are present as functional groups in glycosidic bonds. trans-2-Butenal diethyl acetal has been synthesized from trans-2-butenal with ethanol in the presence of methanesulfonic acid or methylsulfonate as catalysts.[1]

애플리케이션

trans-2-Butenal diethyl acetal may be used in the preparation of 2S,3S-epoxybutan-1-ol, an intermediate in the synthesis of erythromycin antibiotic.[2]

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H226,H315,H319,H335
• 예방조치 성명서: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): 93.2 °F - closed cup
• Flash Point (°C): 34 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter