421804

(1S,2S)-trans-1,2-Cyclohexanediol

99%

• 동의어(들): (1S)-trans-1,2-Cyclohexanediol
• Linear Formula: C₆H₁₀(OH)₂
• CAS Number: 57794-08-8
• Molecular Weight: 116.16
• Beilstein: 1901343
• MDL number: MFCD00066431
• UNSPSC 코드: 12352001
• PubChem Substance ID: 24866402
• NACRES: NA.22

속성

• Quality Level: 200
• 분석: 99%
• 광학 활성: [α]20/D +39°, c = 1.6 in H₂O
• 광학 순도: ee: 99% (GLC)
• mp: 107-109 °C (lit.)
• 작용기: hydroxyl
• SMILES string: O[C@H]1CCCC[C@@H]1O
• InChI: 1S/C6H12O2/c7-5-3-1-2-4-6(5)8/h5-8H,1-4H2/t5-,6-/m0/s1
• InChI key: PFURGBBHAOXLIO-WDSKDSINSA-N

설명

애플리케이션

(1S,2S)-trans-1,2-Cyclohexanediol may be used in the preparation of (1S,2S)-1,2-cyclohexanediyl bis(4-vinylbenzoate) by reacting with 4-vinylbenzoyl chloride.[1] It may also be used as a chiral ligand for the preparation of non-racemic hydroxy phosphonates via titanium alkoxide-catalyzed addition of dimethyl phosphite to the corresponding aldehydes.[2]

C₂-symmetric chiral diol with versatile applications as a chiral auxiliary,[3][4] building block,[5][6][7] and chiral ligand.[8][9]

안전성 정보

• 픽토그램: GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H318,H335
• 예방조치 성명서: P261 - P280 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1 - STOT SE 3
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves