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Merck
모든 사진(1)

문서

42135

Sigma-Aldrich

1,5-Dinitronaphthalene

≥97.0% (HPLC)

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About This Item

Linear Formula:
C10H6(NO2)2
CAS Number:
Molecular Weight:
218.17
Beilstein:
527184
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:

분석

≥97.0% (HPLC)

형태

powder

mp

213-216 °C (lit.)
214-217 °C

SMILES string

[O-][N+](=O)c1cccc2c(cccc12)[N+]([O-])=O

InChI

1S/C10H6N2O4/c13-11(14)9-5-1-3-7-8(9)4-2-6-10(7)12(15)16/h1-6H

InChI key

ZUTCJXFCHHDFJS-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

1,3-Dinitronaphthalene, 1,5-dinitronaphthalene and 1,8-dinitronaphthalene are the three dinitronaphthalene isomers. Their photocatalytic oxidation reactions in the presence of TiO2 Degussa P-25 grade has been investigated. 1,5-Dinitronaphthalene has been reported as environmental pollutant. Its genotoxic effects during in vivo wing somatic mutation and recombination test (SMART) of Drosophila melanogaster has been investigated. Delocalized intervalence radical anions of 1,5-dinitronaphthalene exhibits charge-transfer bands in their near-IR spectra. Crystals of 1,5-dinitronaphthalene are reported to be monoclinic with two molecules in each unit cell.

애플리케이션

1,5-Dinitronaphthalene has been employed as standard for the analysis of compounds of environmental interest by new nano-high-performance liquid chromatography-electron ionization mass spectrometry.

픽토그램

Health hazardCorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


시험 성적서(COA)

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문서 라이브러리 방문

Kei Miyazawa et al.
Journal of mass spectrometry : JMS, 55(12), e4668-e4668 (2020-11-03)
Fragmentation of peptide radical cations [M]. + has been examined using matrix-assisted laser desorption/ionization (MALDI) in-source decay (ISD) with hydrogen-abstracting nitro-substituted matrices. The ISD spectra of peptides containing an arginine (Arg) residue at carboxyl (C)-termini showed preferential [w]+ ions when
Nano-high-performance liquid chromatography-electron ionization mass spectrometry approach for environmental analysis.
Cappiello A, et al.
Analytica Chimica Acta, 493(2), 125-136 (2003)
Yuki Hiruta et al.
The Analyst, 141(3), 910-917 (2015-12-10)
Temperature-responsive polymers incorporating molecular-recognition sites were developed as stationary phases for high-performance liquid chromatography (HPLC). The grafted stationary phases consisted of functional copolymers composed of N-isopropylacrylamide (NIPAAm) and N-acryloyl aromatic amino acid methyl esters, i.e., phenylalanine and tryptophan methyl esters
The crystal structure of 1, 5-dinitronaphthalene.
Trotter J.
Acta Crystallographica, 13(2), 95-99 (1960)
Stephen F Nelsen et al.
Journal of the American Chemical Society, 125(41), 12493-12501 (2003-10-09)
The Class III (delocalized) intervalence radical anions of 1,4-dinitrobenzene, 2,6-dinitronaphthalene, 2,6-dinitroanthracene, 9,9-dimethyl-2,7-dinitrofluorene, 4,4'-dinitrobiphenyl, and 1,5-dinitronaphthalene show charge-transfer bands in their near-IR spectra. The dinitroaromatic radical anions have comparable but slightly larger electronic interactions (H(ab) values) through the same aromatic bridges

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