420697

N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine

96%

• 동의어(들): N-(Methoxymethyl)-N-(trimethylsilylmethyl)-N-benzylamine, N-Benzyl-N-(methoxymethyl)trimethylsilylmethylamine, Benzyl(methoxymethyl)[(trimethylsilyl)methyl]amine
• Linear Formula: C₆H₅CH₂N(CH₂OCH₃)CH₂Si(CH₃)₃
• CAS Number: 93102-05-7
• Molecular Weight: 237.41
• MDL number: MFCD00674005
• UNSPSC 코드: 12352116
• PubChem Substance ID: 24866346
• NACRES: NA.22

속성

• 분석: 96%
• 형태: liquid
• refractive index: n20/D 1.492 (lit.)
• bp: 76 °C/0.3 mmHg (lit.)
• density: 0.928 g/mL at 25 °C (lit.)
• SMILES string: COCN(Cc1ccccc1)C[Si](C)(C)C
• InChI: 1S/C13H23NOSi/c1-15-11-14(12-16(2,3)4)10-13-8-6-5-7-9-13/h5-9H,10-12H2,1-4H3
• InChI key: RPZAAFUKDPKTKP-UHFFFAOYSA-N

설명

애플리케이션

Forms azomethine ylides which readily undergo [3+2] cycloaddition to α,ß-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields.

Reacted in asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): 150.8 °F - closed cup
• Flash Point (°C): 66 °C - closed cup
• 개인 보호 장비: Eyeshields, Gloves, type ABEK (EN14387) respirator filter