407690

tert-Butyl N-(benzyloxy)carbamate

99%

• Linear Formula: C₆H₅CH₂ONHCO₂C(CH₃)₃
• CAS Number: 79722-21-7
• Molecular Weight: 223.27
• MDL number: MFCD00191873
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24865479

속성

• 분석: 99%
• mp: 45-47 °C (lit.)
• 작용기: amine; phenyl
• SMILES string: CC(C)(C)OC(=O)NOCc1ccccc1
• InChI: 1S/C12H17NO3/c1-12(2,3)16-11(14)13-15-9-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3,(H,13,14)
• InChI key: MZNBNPWFHGWAGH-UHFFFAOYSA-N

설명

일반 설명

tert-Butyl N-(benzyloxy)carbamate (tert-butyl benzyloxycarbamate), a protected hydroxylamine,[1] is an N-alkyl-N-benzyloxy carbamate.[2] Its C-N cross coupling reaction with fluorescein ditriflate has been reported.[1] It participates in facile intramolecular cyclization with various carbon nucleophiles to afford functionalized 5- and 6-membered protected cyclic hydroxamic acids.[2]

애플리케이션

tert-Butyl N-(benzyloxy)carbamate was used in the preparation of seven-membered cyclic hydroxamic acids.[2] It may be used in the synthesis of 2-(N-formyl-N-hydroxyamino) ethylphosphonate (IPP).[3]

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves