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Merck
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주요 문서

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392499

Sigma-Aldrich

1-Iodo-3,4-dimethylbenzene

99%

동의어(들):

4-Iodo-o-xylene

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About This Item

Linear Formula:
(CH3)2C6H3I
CAS Number:
31599-61-8
Molecular Weight:
232.06
MDL number:
MFCD00040989
UNSPSC 코드:
12352100
PubChem Substance ID:
24864459
NACRES:
NA.22

분석

99%

양식

liquid

refractive index

n20/D 1.603 (lit.)

bp

106-108 °C/13 mmHg (lit.)

density

1.633 g/mL at 25 °C (lit.)

SMILES string

Cc1ccc(I)cc1C

InChI

1S/C8H9I/c1-6-3-4-8(9)5-7(6)2/h3-5H,1-2H3

InChI key

CSFRCLYFVINMBZ-UHFFFAOYSA-N

일반 설명

1-Iodo-3,4-dimethylbenzene (4-iodo-o-xylene, 3,4-dimethyliodobenzene) is an aryl halide. Its synthesis, NMR and IR spectra has been reported.[1] Its nitration reaction[2] and copper catalyzed trifluoromethylation reaction has been studied.[3]

애플리케이션

1-Iodo-3,4-dimethylbenzene (4-iodo-o-xylene, 3,4-dimethyliodobenzene) may be used in the synthesis of the following:
  • 3-arylacrylamide[4]
  • 3,3-diaryl substituted acrylamide[4]
  • 3-arylpropylamine[4]
  • di-tert-butyl 1-(3,4-dimethylphenyl)hydrazine-1,2-dicarboxylate[5]
  • 2,3,7,8-tetramethyldibenzofuran[6]
  • N-(3-(3,4-Dimethylphenyl)-2-phthalimidopropionyl)-2-methylthioaniline[7]

픽토그램

Exclamation mark
GHS07

신호어

Warning

유해 및 위험 성명서

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

235.4 °F - closed cup

Flash Point (°C)

113 °C - closed cup

개인 보호 장비

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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시험 성적서(COA)

Lot/Batch Number
BCBZ3703
BCBV3009
BCBS8568V
BCBQ4077V
BCBM3839V

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문서 라이브러리 방문

이미 열람한 고객

Slide 1 of 2

1 of 2

4-Iodoanisole 98%

Sigma-Aldrich

I7608

4-Iodoanisole

o-Xylene anhydrous, 97%

Sigma-Aldrich

294780

o-Xylene

Martyn Inman et al.
The Journal of organic chemistry, 77(3), 1217-1232 (2011-10-08)
In a new variation on the Fischer indole synthesis, readily available haloarenes are converted into a wide range of indoles in just two steps by halogen-magnesium exchange and quenching with di-tert-butyl azodicarboxylate, followed by reaction with aldehydes or ketones under
ipso-Nitration of 4-iodo-o-xylene.
Zweig A, et al.
The Journal of Organic Chemistry, 42(25), 4049-4052 (1977)
Dmitry Shabashov et al.
Journal of the American Chemical Society, 132(11), 3965-3972 (2010-02-24)
We have developed a method for auxiliary-directed, palladium-catalyzed beta-arylation and alkylation of sp(3) and sp(2) C-H bonds in carboxylic acid derivatives. The method employs a carboxylic acid 2-methylthioaniline- or 8-aminoquinoline amide substrate, aryl or alkyl iodide coupling partner, palladium acetate
Towards a practical and efficient copper-catalyzed trifluoromethylation of aryl halides.
Schareina T, et al.
Topics in Catalysis, 55(7-10), 426-431 (2012)
Efficient and direct iodination of alkyl benzenes using polymer/HIO4 and I2 under mild condition.
Pourali AR, et al.
Bulletin of the Chemical Society of Ethiopia, 28(2), 305-308 (2014)
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