389471

Ethyltriphenylphosphonium iodide

95%

• 동의어(들): ETPPI, Phenylphosphonium ethyl iodide
• Linear Formula: (C₆H₅)₃P(I)C₂H₅
• CAS Number: 4736-60-1
• Molecular Weight: 418.25
• Beilstein: 3659323
• EC Number: 225-245-2
• MDL number: MFCD00040352
• UNSPSC 코드: 12352002
• PubChem Substance ID: 24864288
• NACRES: NA.22

속성

• 분석: 95%
• 형태: powder
• 반응 적합성: reaction type: C-C Bond Formation
• mp: 164-168 °C (lit.)
• SMILES string: [I-].CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C20H20P.HI/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20;/h3-17H,2H2,1H3;1H/q+1;/p-1
• InChI key: SLAFUPJSGFVWPP-UHFFFAOYSA-M

설명

애플리케이션

Ethyltriphenylphosphonium iodide can be used as:

• An efficient catalyst for N,N-dimethylation of primary aromatic amines with methyl alkyl carbonates.
• A phase transfer catalyst for the synthesis of 3-hydroxyflavones from chalcones via Algar−Flynn−Oyamada synthesis.

Reactant involved in:

• Synthesis of diarylmethine derivatives, phosphonium salts, and bismuth(III) polynuclear halide complexes
• Asymmetric hydrogenation

안전성 정보

• 픽토그램: GHS06
• 신호어: Danger
• 유해 및 위험 성명서: H301,H319
• 예방조치 성명서: P264 - P280 - P301 + P310 - P305 + P351 + P338 - P337 + P313 - P405
• Hazard Classifications: Acute Tox. 3 Oral - Eye Irrit. 2
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges