381020

tert-Butyldichlorophosphine

98%

• 동의어(들): tert-Butylphosphine dichloride, tert-Butylphosphonous dichloride
• Linear Formula: (CH₃)₃CPCl₂
• CAS Number: 25979-07-1
• Molecular Weight: 158.99
• EC Number: 247-386-9
• MDL number: MFCD00013615
• UNSPSC 코드: 12352001
• PubChem Substance ID: 24863784
• NACRES: NA.22

속성

• 분석: 98%
• 반응 적합성: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling
• mp: 44-49 °C (lit.)
• 작용기: phosphine
• SMILES string: CC(C)(C)P(Cl)Cl
• InChI: 1S/C4H9Cl2P/c1-4(2,3)7(5)6/h1-3H3
• InChI key: NMJASRUOIRRDSX-UHFFFAOYSA-N

설명

애플리케이션

tert-Butyldichlorophosphine can be used as a reactant for the synthesis of:

• Dihydrobenzooxaphosphole core.[1]
• tert-Butyl functionalized 1,3-C₆H₄(CH₂PR₂)₂ (PCP) pincer ligands.[2]
• Chloro-phosphinite reagent by reacting with sodium ethoxide.[3]
• 2-(tert-Butylhydrophosphoryl)-1-phenyl-1H-imidazole derivatives.[4]

안전성 정보

• 픽토그램: GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H314
• 예방조치 성명서: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• 보충제 위험성: EUH014
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges