추천 제품
Quality Level
분석
98%
양식
solid
반응 적합성
core: titanium
reagent type: catalyst
bp
230 °C (lit.)
mp
38-40 °C (lit.)
density
3.25 g/mL at 25 °C (lit.)
SMILES string
Br[Ti](Br)(Br)Br
InChI
1S/4BrH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
UBZYKBZMAMTNKW-UHFFFAOYSA-J
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애플리케이션
Titanium(IV) bromide (Titanium tetrabromide or TiBr4) can be employed as a Lewis acid catalyst in the synthesis of:
- α-bromomethylene aldols by reacting with arylaldehydes and but-3-yn-2-one via Baylis-Hillman reaction.
- Titanium(II) bromide which along with copper forms an efficient catalytic system for Pinacol reaction.
- α-bromo-γ-hydroxyenamides by the reaction of ynamides and aldehyde or ketones.
특징 및 장점
Used for the formation of titanium silicide thin films on Si substrates.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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시험 성적서(COA)
Lot/Batch Number
이미 열람한 고객
Titanium (IV) Bromide and Boron (III) Tribromide Promoted Baylis-Hillman Reactions of Arylaldehydes with But-3-yn-2-one
Shi M and Wang C-J
Helvetica Chimica Acta, 85(3), 841-846 (2002)
Efficient diastereoselective pinacol reaction of aliphatic and aromatic aldehydes by combined use of newly utilized titanium (II) bromide and copper
Mukaiyama T, et al.
Chemistry Letters (Jpn), 29(4), 336-337 (2000)
Synthesis of α-Halo-γ -hydroxyenamides by Titanium Tetrahalide Mediated Addition of Aldehydes or Ketones to Ynamides
Yabuuchi Y, et al.
Organic Letters, 18(19), 4951-4953 (2016)
K Sellschopp et al.
The Journal of chemical physics, 152(6), 064702-064702 (2020-02-18)
The ability to synthesize nanoparticles (NPs), here TiO2, of different shapes in a controlled and reproducible way is of high significance for a wide range of fields including catalysis and materials design. Different NP shapes exhibit variations of emerging facets
문서
Titanium dioxide applications: Semiconducting material characteristics and diverse functionalities.
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