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Merck
모든 사진(1)

주요 문서

302937

Sigma-Aldrich

Perfluoro(methylcyclohexane)

technical grade, 90%

동의어(들):

(Trifluoromethyl)undecafluorocyclohexane, Perfluoromethylcyclohexane

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25 G
₩120,684
100 G
₩358,701

₩120,684


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25 G
₩120,684
100 G
₩358,701

About This Item

Linear Formula:
C6F11CF3
CAS Number:
Molecular Weight:
350.05
Beilstein:
1915981
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

₩120,684


구입 가능 여부는 고객센터에 문의하십시오.

벌크 견적 요청

Grade

technical grade

분석

90%

양식

liquid

refractive index

n17/D 1.285 (lit.)

bp

76 °C (lit.)

density

1.787 g/mL at 25 °C (lit.)

작용기

fluoro

SMILES string

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F

InChI

1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12

InChI key

QIROQPWSJUXOJC-UHFFFAOYSA-N

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일반 설명

Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions.[1] Gas-phase structure of perfluoro(methylcyclohexane) was investigated.[2]

애플리케이션

Perfluoro(methylcyclohexane) can be used as:
  • A reactant to synthesize perfluoro-2-methylcyclohex-1-enolate by photochemical reaction with tetrabutylammonium iodide in water.[3]
  • A fluorous solvent to synthesize polynorbornene via ring-opening metathesis polymerization (ROMP) of norbornene using fluorous Grubbs′ second-generation catalyst.[4]

It can also be used as a solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.[5]
Perfluoro(methylcyclohexane) was employed as solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.[5]

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves


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문서 라이브러리 방문

Development of Highly Active Ring Opening Metathesis Polymerization Catalyst Systems-A New Approach for Green Catalyst Design
Tuba R, et al.
Proceedings, 2011(1), EVO3-EVO3 (2011)
Mei-Jy Jeng et al.
Critical care medicine, 34(4), 1099-1105 (2006-02-18)
To investigate the therapeutic effects of bronchoalveolar lavage (BAL) with either diluted surfactant (SBAL) or perfluorochemical liquid (PBAL), followed by either conventional mechanical ventilation (CMV) or partial liquid ventilation (PLV), on lung injury and proinflammatory cytokine production induced by meconium
Stephanie S Adkins et al.
The journal of physical chemistry. B, 112(15), 4760-4769 (2008-03-28)
The technique of hydrophobic ion pairing was used to solubilize the lipase from Candida rugosa in a fluorinated solvent, perfluoromethylcyclohexane (PFMC), in complex with a perfluoropolyether (PFPE) surfactant, KDP 4606. The enzyme-surfactant complex was determined to have a hydrodynamic diameter
Functionalization of saturated fluorocarbons with and without light
Chen X and Lemal DM
Journal of Fluorine Chemistry, 127(9), 1158-1167 (2006)
Miharu Koshino et al.
Ultrasonics sonochemistry, 54, 250-255 (2019-02-05)
We have developed a new emulsion template method for the synthesis of poly(methylmethacrylate) (PMMA) hollow nanoparticles with different sizes. This synthetic method involves sequential ultrasonic irradiation (20 kHz → 500 kHz → 1.6 MHz → 2.4 MHz → 5.0 MHz) for acoustic emulsification of a water-insoluble fluorous solvent such as perfluoromethylcyclohexane (PFMCH) in

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