추천 제품
농도
50 wt. % suspension in toluene
bp
400 °C (lit.)
mp
210 °C (lit.)
SMILES string
N[Na]
InChI
1S/H2N.Na/h1H2;/q-1;+1
InChI key
ODZPKZBBUMBTMG-UHFFFAOYSA-N
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일반 설명
Sodium amide, an inorganic compound used in organic synthesis, is generally prepared by heating sodium metal in gaseous ammonia. It is used in some organic reactions like dehalogenation, deprotonation, anionic polymerization of ionic chains, and in cleavage of ketones.
애플리케이션
Reagent for:
Synthesis of allylic amines and amides
Synthesis of antibacterials
Aggregative activation and heterocyclic chemistry
Phenylation with diphenyliodonium chloride
Synthesis of allylic amines and amides
Synthesis of antibacterials
Aggregative activation and heterocyclic chemistry
Phenylation with diphenyliodonium chloride
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 2
표적 기관
Central nervous system
보충제 위험성
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point (°F)
39.2 °F - closed cup
Flash Point (°C)
4 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
이미 열람한 고객
Sodium Amide
Ullmann's Encyclopedia of Industrial Chemistry (2000)
M. Bakavoli, et al.,
Journal of Heterocyclic Chemistry, 48, 149-152 (2010)
Christian Bukovec et al.
Organic & biomolecular chemistry, 9(8), 2743-2750 (2011-03-08)
Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized building blocks
K. G. Hampton, et al.,
Organic Syntheses, 51, 128-132 (1971)
C. Caubere, et al.,
Tetrahedron, 50, 11903-11920 (1994)
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