모든 사진(1)
About This Item
실험식(Hill 표기법):
C10H14O2
CAS Number:
Molecular Weight:
166.22
Beilstein:
2327696
MDL number:
UNSPSC 코드:
12352115
PubChem Substance ID:
NACRES:
NA.22
추천 제품
분석
99%
광학 활성
[α]20/D −101°, c = 2 in toluene
mp
200-203 °C (lit.)
SMILES string
CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2=O
InChI
1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10+/m1/s1
InChI key
VNQXSTWCDUXYEZ-LDWIPMOCSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
(1R)-(−)-Camphorquinone can be used as a chiral starting material for the preparation of:
- α-Hydroxycamphors by selective reduction of keto groups using various vegetables.
- Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies.
- Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents.
- Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Resp. Sens. 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
Enantioselective transfer aminoallylation: synthesis of optically active homoallylic primary amines.
Masaharu Sugiura et al.
Journal of the American Chemical Society, 128(34), 11038-11039 (2006-08-24)
A camphorquinone-derived chiral homoallylic amine was found to react with various aldehydes via imine formation and asymmetric 2-azonia-Cope rearrangement to give optically active homoallylic primary amines. A practical level of enantioselectivity with high functional group tolerance has been attained in
Stereoselective reduction of ketones by various vegetables
Utsukihara T, et al.
Journal of Molecular Catalysis. B, Enzymatic, 41(3-4), 103-109 (2006)
Angel M Montaña et al.
Bioorganic & medicinal chemistry, 16(4), 1721-1737 (2007-11-27)
The platinum(II) complex cis-[(1S,2R,3S)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-diamine]dichloroplatinum(II) (1) and its enantiomer (2) have been synthesized and physically and spectroscopically characterized. To obtain the enantiopure complexes the chiral pool approach was applied. The synthetic pathway has four steps, starting from (+/-)-diphenylethylenediamine (DPEDA) (3) and
Synthesis of camphoric anhydride via unsensitized photo-oxidation of camphorquinone
Shun-Jun J, et al.
Synthetic Communications, 32(11), 1659-1663 (2002)
Tetrahedron Asymmetry, 17, 1179-1179 (2006)
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