255025

Hexylmagnesium bromide solution

2.0 M in diethyl ether

• 동의어(들): 1-Hexylmagnesium bromide, Bromohexylmagnesium, n-hexylmagnesium bromide
• Linear Formula: CH₃(CH₂)₅MgBr
• CAS Number: 3761-92-0
• Molecular Weight: 189.38
• Beilstein: 3535624
• MDL number: MFCD00000046
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24855279
• NACRES: NA.22

속성

• 반응 적합성: reaction type: Grignard Reaction
• 농도: 2.0 M in diethyl ether
• density: 0.965 g/mL at 25 °C
• SMILES string: CCCCCC[Mg]Br
• InChI: 1S/C6H13.BrH.Mg/c1-3-5-6-4-2;;/h1,3-6H2,2H3;1H;/q;;+1/p-1
• InChI key: SFXUWNMDTWQSHE-UHFFFAOYSA-M

설명

일반 설명

Hexylmagnesium bromide, also known as n-hexylmagnesium bromide, is a useful organomagnesium compound that is commonly used in organic synthesis. It is typically prepared by reacting magnesium turnings with 1-bromohexane in diethyl ether solvent.

애플리케이션

Hexylmagnesium bromide solution can be used as a reagent in addition reactions. It can add to various electrophiles, such as carbonyl compounds, to form alcohols or carboxylic acids. These types of reactions are commonly used for the synthesis of pharmaceuticals, natural products, and other organic compounds. It is also used to reduce certain functional groups, such as ketones, esters, and nitriles, to form alcohols or amines.

안전성 정보

• 픽토그램: GHS02,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H260,H302,H314,H336
• 예방조치 성명서: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• 표적 기관: Central nervous system
• 보충제 위험성: EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point (°F): -40.0 °F - closed cup
• Flash Point (°C): -40 °C - closed cup
• 개인 보호 장비: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter