250376

4-Formylmorpholine

99%

• 동의어(들): 4-Morpholinecarboxaldehyde
• 실험식(Hill 표기법): C₅H₉NO₂
• CAS Number: 4394-85-8
• Molecular Weight: 115.13
• Beilstein: 110293
• EC Number: 224-518-3
• MDL number: MFCD00006170
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24855051
• NACRES: NA.22

속성

• 분석: 99%
• 양식: solid
• refractive index: n20/D 1.485 (lit.)
• bp: 236-237 °C (lit.)
• mp: 20-23 °C (lit.)
• density: 1.145 g/mL at 25 °C (lit.)
• 작용기: ether
• SMILES string: [H]C(=O)N1CCOCC1
• InChI: 1S/C5H9NO2/c7-5-6-1-3-8-4-2-6/h5H,1-4H2
• InChI key: LCEDQNDDFOCWGG-UHFFFAOYSA-N

설명

일반 설명

Treatment of 4-formylmorpholine with sulphur tetrafluoride in the presence of potassium fluoride gives 4-(trifluoromethyl)morpholine in excellent yields[1]. 4-Formylmorpholine reacts with series of 2-alkyl-2-cyclohexen-1-ones in the presence of POCl₃ to give the corresponding 3-alkyl-2-chloro-5,6-dihydrobenzaldehydes and allylic alcohols (by-product)[2].

애플리케이션

4-Formylmorpholine has been used in the preparation of:

• adenine hydrochloride labelled with ¹⁴C[3]
• terphenyl dialdehyde[4]

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H317
• 예방조치 성명서: P261 - P272 - P280 - P302 + P352 - P333 + P313 - P362 + P364
• Hazard Classifications: Skin Sens. 1
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 1
• Flash Point (°F): 244.4 °F - DIN 51758
• Flash Point (°C): 118 °C - DIN 51758
• 개인 보호 장비: Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)