237582

Methyl 2-phenylsulfinylacetate

98%

• Linear Formula: C₆H₅S(O)CH₂CO₂CH₃
• CAS Number: 14090-83-6
• Molecular Weight: 198.24
• Beilstein: 1953383
• EC Number: 237-936-6
• MDL number: MFCD00002087
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24854255
• NACRES: NA.22

속성

• 분석: 98%
• 양식: solid
• bp: 130-131 °C/0.5 mmHg (lit.)
• mp: 52-54 °C (lit.)
• SMILES string: COC(=O)CS(=O)c1ccccc1
• InChI: 1S/C9H10O3S/c1-12-9(10)7-13(11)8-5-3-2-4-6-8/h2-6H,7H2,1H3
• InChI key: JPPXZUDQIXZLIL-UHFFFAOYSA-N

설명

일반 설명

Anion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides.

애플리케이션

Anion of methyl 2-phenylsulfinylacetate has been employed in the synthesis of α,β-unsaturated esters.

안전성 정보

• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point (°F): 235.4 °F - closed cup
• Flash Point (°C): 113 °C - closed cup
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)