225916

Benzylmagnesium chloride solution

2.0 M in THF

• 동의어(들): (Phenylmethyl)magnesium chloride, Benzylchloromagnesium, Chloro(phenylmethyl)magnesium
• Linear Formula: C₆H₅CH₂MgCl
• CAS Number: 6921-34-2
• Molecular Weight: 150.89
• Beilstein: 878506
• MDL number: MFCD00000469
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24853532
• NACRES: NA.22

속성

• Quality Level: 100
• 반응 적합성: reaction type: Grignard Reaction
• 농도: 2.0 M in THF
• density: 1.031 g/mL at 25 °C
• 작용기: phenyl
• SMILES string: Cl[Mg]Cc1ccccc1
• InChI: 1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
• InChI key: NRAFPLGJPPJUNB-UHFFFAOYSA-M

설명

일반 설명

Benzylmagnesium chloride is an organometallic compound that acts as a Lewis acid and a strong base.

애플리케이션

Benzylmagnesium chloride (Grignard reagent) can be used as an alkylating reagent:

• For alkylating quinolyl-functionalized Cp−chromium(III) complexes which are used as precursors for the preparation of active olefin polymerization catalysts.
• In the synthesis of 2,3-disubstituted benzopyran-4-ones, 6-chloro-8-methylpurine derivative, and phenylalanine derivatives.

안전성 정보

• 픽토그램: GHS02,GHS08,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H314,H335,H336,H351
• 예방조치 성명서: P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Central nervous system, Respiratory system
• 보충제 위험성: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point (°F): 1.4 °F - closed cup
• Flash Point (°C): -17 °C - closed cup
• 개인 보호 장비: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter