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주요 문서

223670

Sigma-Aldrich

Bis(cyclopentadienyl)zirconium(IV) chloride hydride

95%

동의어(들):

Di(cyclopentadienyl)zirconium(IV) chloride hydride, Schwartz’ reagent, Zirconocene chloride hydride

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크기 선택

1 G
₩52,273
5 G
₩248,574
25 G
₩697,001

₩52,273


구입 가능 여부는 고객센터에 문의하십시오.

벌크 견적 요청

크기 선택

보기 변경
1 G
₩52,273
5 G
₩248,574
25 G
₩697,001

About This Item

실험식(Hill 표기법):
C10H11ClZr
CAS Number:
Molecular Weight:
257.87
EC Number:
MDL number:
UNSPSC 코드:
12352101
PubChem Substance ID:
NACRES:
NA.22

₩52,273


구입 가능 여부는 고객센터에 문의하십시오.

벌크 견적 요청

Quality Level

분석

95%

양식

powder

반응 적합성

core: zirconium
reagent type: catalyst
reagent type: reductant

SMILES string

[H][Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.ClH.Zr.H/c2*1-2-4-5-3-1;;;/h2*1-5H;1H;;/q;;;+1;/p-1

InChI key

PSYHEBZUPSHSKK-UHFFFAOYSA-M

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일반 설명

Bis(cyclopentadienyl)zirconium(IV) chloride hydride, also known as Schwartz′s reagent, is utilized as a catalyst in in olefin polymerization.[1]

애플리케이션

Bis(cyclopentadienyl)zirconium(IV) chloride hydride can be used:
  • To convert amides to aldehydes.[2]
  • As a reagent for the functionalization of olefins and alkynes.[3]
  • As a reducing agent in the preparation of (E)-vinyl organochalcogenides.[4]
  • To prepare a dioxaborolane derivative, which is a key intermediate for the synthesis of bridged-nicotine analogs.[5]

픽토그램

FlameCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Skin Corr. 1B - Water-react 2

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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시험 성적서(COA)

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이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Preparation, characterization, and activity of silica supported metallocene catalysts
L Britcher, et al.
Chemistry of Materials, 16, 5713-5720 (2004)
Bruce Ganem et al.
The Journal of organic chemistry, 72(11), 3981-3987 (2007-03-27)
In this Perspective, which describes the achievements recognized by the 2007 ACS Award for Creative Invention, we discuss the discovery of a new synthetic reaction and its translation into a substantially improved method for manufacturing a major pharmaceutical product--the blockbuster
Concise synthesis of new bridged-nicotine analogues
Crestey F, et al.
Tetrahedron, 68(5), 1417-1421 (2012)
Organic Syntheses, 71, 83-83 (1992)
One-pot synthesis of mixed (Z)-1, 2-bis (organylchalcogene)-1-alkenes precursors of the novel beta-organylthio vinyllithium intermediates
Dabdoub MJ, et al.
Tetrahedron Letters, 51(39), 5141-5145 (2010)

질문

1–2 / 2 질문  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 답변
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 답변
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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