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Merck
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주요 문서

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197378

Sigma-Aldrich

Picric acid

moistened with water, ≥98%

동의어(들):

2,4,6-Trinitrophenol, PA

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About This Item

Linear Formula:
(O2N)3C6H2OH
CAS Number:
88-89-1
Molecular Weight:
229.10
색상 지수 번호:
10305
Beilstein:
423400
MDL number:
MFCD00007102
UNSPSC 코드:
12352100
PubChem Substance ID:
57647805
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vapor density

7.9 (vs air)

Quality Level

200

vapor pressure

1 mmHg ( 195 °C)

분석

≥98%

양식

powder or crystals (with a top layer of Liquid)

포함

≥35% water

expl. lim.

0.01 %

농도

≥50-<70%

mp

122-123 °C (dried material) (lit.)

solubility

alcohol: 1 (g/12 mL)(lit.)
benzene: 1 g/10 mL
chloroform: 1 (g/35 mL)
diethyl ether: 1 (g/65 mL)

density

1.763 g/cm3

작용기

nitro

SMILES string

Oc1c(cc(cc1[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C6H3N3O7/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16/h1-2,10H

InChI key

OXNIZHLAWKMVMX-UHFFFAOYSA-N

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관련 카테고리

일반 설명

Picric acid (PA, 2,4,6-trinitrophenol)[1] is a polynitrated aromatic acid. It is strongly acidic in nature. Since it readily dissolves in water, it can easily pollute the environment on exposure.[2] Sensitive detection of PA by tris-imidazolium salt,[2] fluorescent [3+2] self-assembled nanoscopic organic cage[3] and rhodamine based sensors[4] have been reported. It is widely used for the determination of various organic compounds by spectrophotometric and extractive spectrophotometric methods.[1]

애플리케이션

Picric acid has been used in the preparation of Bouin′s fixative[5] and picric acid/sodium azide/multi-walled carbon nanotubes.[6]
Picric acid was used in the quantitative determination of bisoprolol[7].

픽토그램

FlameSkull and crossbones
GHS02,GHS06

신호어

Danger

유해 및 위험 성명서

H206,H302,H311 + H331

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Desen. Expl. 1

Storage Class Code

4.1A - Other explosive hazardous materials

WGK

WGK 2

Flash Point (°F)

302.0 °F - closed cup

Flash Point (°C)

150 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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시험 성적서(COA)

Lot/Batch Number
MKCX5952
MKCX3890
MKCS4635
CDBG5005
MKCS7470

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COA 검색

이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Preparation and evaluation of hybrid composites of chemical fuel and multi-walled carbon nanotubes in the study of thermopower waves.
Hwang H, et al.
Journal of Visualized Experiments, 98, e52818- e52818 (2015)
Mario Sanhueza et al.
Journal of visualized experiments : JoVE, (111)(111), doi:10-doi:10 (2016-05-24)
Most studies on morphogenesis rely on qualitative descriptions of how anatomical traits are affected by the disruption of specific genes and genetic pathways. Quantitative descriptions are rarely performed, although genetic manipulations produce a range of phenotypic effects and variations are
Bijan Roy et al.
The Journal of organic chemistry, 78(3), 1306-1310 (2013-01-12)
Two new anthracene-functionalized fluorescent tris-imidazolium salts have been synthesized, characterized, and proven to be selective sensors for picric acid, which is a common constituent of many powerful explosives. Theoretical studies revealed an unusual ground-state electron transfer from picrate anion to
Koushik Acharyya et al.
Chemical communications (Cambridge, England), 50(99), 15788-15791 (2014-11-06)
Dynamic covalent imine chemistry has been utilized to synthesize a fluorescent [3+2] self-assembled nanoscopic organic cage. The fluorescent nature of the reduced analogue of the cage was further exploited for the highly selective detection of the explosive picric acid (PA).
Alina-Diana Panainte et al.
Revista medico-chirurgicala a Societatii de Medici si Naturalisti din Iasi, 117(2), 520-524 (2013-12-18)
Bisoprolol is a drug belonging to beta blockers drugs used primarily for the treatment of cardiovascular diseases. A spectrophotometric method for quantitative determination of bisoprolol was developed based on the formation of a complex combination between bisoprolol and picric acid.
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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 답변

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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