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Merck
모든 사진(1)

문서

125482

Sigma-Aldrich

cis-Cyclooctene

contains 100-200 ppm Irganox 1076 FD as antioxidant, 95%

동의어(들):

(Z)-Cyclooctene

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About This Item

실험식(Hill 표기법):
C8H14
CAS Number:
Molecular Weight:
110.20
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

95%

형태

liquid

포함

100-200 ppm Irganox 1076 FD as antioxidant

refractive index

n20/D 1.469 (lit.)

bp

145-146 °C (lit.)

mp

−16 °C (lit.)

solubility

H2O: insoluble

density

0.846 g/mL at 25 °C (lit.)

SMILES string

C1CCCC=CCC1

InChI

1S/C8H14/c1-2-4-6-8-7-5-3-1/h1-2H,3-8H2/b2-1-

InChI key

URYYVOIYTNXXBN-UPHRSURJSA-N

일반 설명

cis-Cyclooctene undergoes addition reaction with carbon tetrachloride catalyzed by dichlorotris(triphenylphosphine) ruthenium(II) to yield 1-chloro-4-(trichloromethyl) cyclooctane (1,4-adduct). It undergoes epoxidation catalyzed by molybdenum oxide nanoparticles incorporated in a mesoporous silica shell coated on dense silica-coated magnetite nanoparticles.

애플리케이션

cis-Cyclooctene has been used to study the alkenes chemisorbed on silicon(100) by scanning tunneling microscopy.

기타 정보

Contains cyclooctane

픽토그램

Flame

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Flam. Liq. 3

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point (°F)

77.0 °F - closed cup

Flash Point (°C)

25 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


시험 성적서(COA)

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문서 라이브러리 방문

Radical reactions in the coordination sphere. 4. Addition of carbon tetrachloride to cis-cyclooctene catalyzed by dichlorotris (triphenylphosphine) ruthenium (II).
Matsumoto H, et al.
The Journal of Organic Chemistry, 43(9), 1734-1736 (1978)
Voltage-dependent STM images of covalently bound molecules on Si (100).
Padowitz DF and Hamers RJ.
The Journal of Physical Chemistry B, 102(43), 8541-8545 (1998)
A magnetically recyclable nanocomposite catalyst for olefin epoxidation.
Mohammadreza Shokouhimehr et al.
Angewandte Chemie (International ed. in English), 46(37), 7039-7043 (2007-08-10)
Xiao-Song Xue et al.
Chemical reviews, 117(13), 8622-8648 (2017-03-11)
The most fundamental concepts in chemistry are structure, energetics, reactivity and their inter-relationships, which are indispensable for promoting chemistry into a rational science. In this regard, bond energy, the intrinsic determinant directly related to structure and reactivity, should be most
Anyang Peng et al.
Science advances, 6(5), eaax6637-eaax6637 (2020-02-18)
Traditionally, a catalyst functions by direct interaction with reactants. In a new noncontact catalytic system (NCCS), an intermediate produced by one catalytic reaction serves as an intermediary to enable an independent reaction to proceed. An example is the selective oxidation

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