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주요 문서

COO/COA

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111910

2-Chlorotoluene

Name: 2-Chlorotoluene
Brand: ALDRICH
Price: 53389 KRW
Availability: InStock

99%

동의어(들):

1-chloro-2-methylbenzene

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크기 선택

100 G

₩53,389

1 KG

₩121,191

4 KG

₩344,593

₩53,389

출고 가능일2025년 4월 23일세부사항

벌크 견적 요청

모든 사진(3)

크기 선택

보기 변경

100 G

₩53,389

1 KG

₩121,191

4 KG

₩344,593

About This Item

Linear Formula:

CH₃C₆H₄Cl

CAS Number:

95-49-8

Molecular Weight:

126.58

Beilstein:

1904175

EC Number:

202-424-3

MDL number:

MFCD00000562

UNSPSC 코드:

12352100

eCl@ss:

39050205

PubChem Substance ID:

24847049

NACRES:

NA.22

₩53,389

출고 가능일2025년 4월 23일세부사항

벌크 견적 요청

추천 제품

Slide 1 of 10

1 of 10

Sigma-Aldrich

111929

4-Chlorotoluene

Sigma-Aldrich

138509

3-Chlorotoluene

Sigma-Aldrich

145009

2,4-Dichlorotoluene

PH010961

2-chloro-1,3,5-trimethylbenzene

Sigma-Aldrich

B82200

4-Bromotoluene

Sigma-Aldrich

167215

3-Bromotoluene

Sigma-Aldrich

B82006

2-Bromotoluene

Sigma-Aldrich

112216

4-Chlorobenzaldehyde

Sigma-Aldrich

185558

Benzyl chloride

Sigma-Aldrich

C28898

2-Chlorobutane

vapor density

4.38 (vs air)

Quality Level

100

vapor pressure

10 mmHg ( 43 °C)

분석

99%

양식

liquid

refractive index

n20/D 1.525 (lit.)

bp

157-159 °C (lit.)

mp

−36 °C (lit.)

solubility

H₂O: soluble

density

1.083 g/mL at 25 °C (lit.)

작용기

chloro

SMILES string

Cc1ccccc1Cl

InChI

1S/C7H7Cl/c1-6-4-2-3-5-7(6)8/h2-5H,1H3

InChI key

IBSQPLPBRSHTTG-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

2-Chlorotoluene can be mineralized completely by Rhodococcus, strain OCT 10 DSM 45596(T)[1]. It is used in the preparation of 3-chloro-4-methylcatechol and 4-chloro-3-methylcatechol[2]. The oxidation of 2-chlorotoluene is very well catalyzed by the enzymes: toluene dioxygenase of P. putida F1 and chlorobenzene dioxygenase from Burkholderia, strain PS12[3].

애플리케이션

2-Chlorotoluene can be used as a precursor to synthesize aryl coupling products via palladium-catalyzed Negishi cross-coupling.[4] It can also be used in the Buchwald-Hartwig amination to synthesize arylamines.[5][6]

픽토그램

GHS02,GHS08,GHS07,GHS09

신호어

Warning

유해 및 위험 성명서

H226,H332,H361d,H410

예방조치 성명서

P202 - P210 - P233 - P273 - P304 + P340 + P312 - P308 + P313

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 2 - Flam. Liq. 3 - Repr. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point (°F)

109.4 °F - closed cup

Flash Point (°C)

43 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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시험 성적서(COA)

Lot/Batch Number

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COA 검색

이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Metabolism of Chlorotoluenes by Burkholderia sp. Strain PS12 and Toluene Dioxygenase of Pseudomonas putida F1: Evidence for Monooxygenation by Toluene and Chlorobenzene Dioxygenases.

A Lehning et al.

Applied and environmental microbiology, 63(5), 1974-1979 (1997-05-01)

The degradation of toluene by Pseudomonas putida F1 and of chlorobenzenes by Burkholderia sp. strain PS12 is initiated by incorporation of dioxygen into the aromatic nucleus to form cis-dihydrodihydroxybenzenes. Toluene-grown cells of P. putida F1 and 3-chlorobenzoate-grown cells of Burkholderia

NIXANTPHOS: A Highly Active Ligand for Palladium Catalyzed Buchwald-Hartwig Amination of Unactivated Aryl Chlorides.

Mao J, et al.

Dalton Transactions, (26) (2018)

The first general method for palladium-catalyzed Negishi cross-coupling of aryl and vinyl chlorides: use of commercially available Pd (P (t-Bu) 3) 2 as a catalyst

Dai C, et al.

Journal of the American Chemical Society, 123(12), 2719-2724 (2001)

Flexible Steric Bulky Bis (Imino) acenaphthene (BIAN)-Supported N-Heterocyclic Carbene Palladium Precatalysts: Catalytic Application in Buchwald?Hartwig Amination in Air.

Lan X B, et al.

The Journal of Organic Chemistry, 82(6), 2914-2925 (2017)

Chloromethylmuconolactones as critical metabolites in the degradation of chloromethylcatechols: recalcitrance of 2-chlorotoluene.

Katrin Pollmann et al.

Journal of bacteriology, 187(7), 2332-2340 (2005-03-19)

To elucidate possible reasons for the recalcitrance of 2-chlorotoluene, the metabolism of chloromethylcatechols, formed after dioxygenation and dehydrogenation by Ralstonia sp. strain PS12 tetrachlorobenzene dioxygenase and chlorobenzene dihydrodiol dehydrogenase, was monitored using chlorocatechol dioxygenases and chloromuconate cycloisomerases partly purified from

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2달 전

How can I determine the shelf life / expiration / retest date of this product?

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1. Technical Support
  
  2달 전
  
  If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
  For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
  For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
  For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
  
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2달 전

How is shipping temperature determined? And how is it related to the product storage temperature?

1 답변
1. Technical Support
  
  2달 전
  
  Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
  
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주요 문서

2-Chlorotoluene

99%

크기 선택

크기 선택

About This Item

추천 제품

속성

vapor density

Quality Level

vapor pressure

분석

양식

refractive index

bp

mp

solubility

density

작용기

SMILES string

InChI

InChI key

관련 카테고리

설명

일반 설명

애플리케이션

안전성 정보

픽토그램

신호어

유해 및 위험 성명서

예방조치 성명서

Hazard Classifications

Storage Class Code

WGK

Flash Point (°F)

Flash Point (°C)

개인 보호 장비

문서

시험 성적서(COA)

이 제품을 이미 가지고 계십니까?

관련 참고 논문

질문

How can I determine the shelf life / expiration / retest date of this product?

How is shipping temperature determined? And how is it related to the product storage temperature?

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활성 필터

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