Skip to Content
Merck
All Photos(1)

Documents

G000594

HPLC Analysis of Bronchodilators Theophylline and Other Caffeine Metabolites in Serum on Discovery® RP-AmideC16 after SPE using Discovery® DSC-18

application for SPE, application for HPLC

Sign Into View Organizational & Contract Pricing


About This Item

technique(s)

HPLC: suitable
solid phase extraction (SPE): suitable

test parameters

sample preparation: SPE (Solid Phase Extraction)
SPE tube/cartridge: Discovery® DSC-18, 500 mg/3 mL (52603-U)
condition: 2 mL methanol, then 2 mL water
sample preparation: 1 mL porcine serum spiked with 0.1 μg/mL, 0.50 μg/mL, or 1.0 μg/mL each analyte
sample preparation: 1 mL methanol; evaporate to dryness with nitrogen stream at room temperature; reconstitute in 200 μL mobile phase containing 0.2 μg/mL or 7-methylxanthine (IS)
sample preparation: 2 mL 5% methanol in water; dry tube 10 min with nitrogen stream
column: Discovery RP-AmideC16, 15 cm × 4.6 mm, 5 μm particles, preceded by a 2 cm RP-AmideC16 guard column and 0.5 μm frit filter (505013)
mobile phase: [A] Methanol; [B] 1% acetic acid (17:38, A:B)
flow rate: 1 mL/min
column temp.: 30 °C
detector: UV, 272 nm
injection: 20 μL reconstituted porcine serum extract

suitability

application for HPLC
application for SPE

application(s)

clinical
pharmaceutical (small molecule)

Legal Information

Discovery is a registered trademark of Merck KGaA, Darmstadt, Germany

Analyte

Description

    Caffeine
    Theobromine
    Theophylline
    7-Methylxanthine, ≥98.0% (HPLC)
    1,7-Dimethylxanthine, ~98%, solid

SPE tube or plate

analytical column


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Sorry, we don't have COAs for this product available online at this time.

If you need assistance, please contact Customer Support.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service