63095

Magnesium perchlorate

puriss. p.a., drying agent, ACS reagent, ≥98.0% (calc. based on dry substance, KT)

• Linear Formula: Mg(ClO₄)₂
• CAS Number: 10034-81-8
• Molecular Weight: 223.21
• EC Number: 233-108-3
• MDL number: MFCD00011102
• UNSPSC Code: 12352300
• PubChem Substance ID: 329759783
• NACRES: NB.24
• form: powder or chunks

Properties

• grade: ACS reagent; puriss. p.a.
• Assay: ≥98.0% (calc. based on dry substance, KT)
• form: powder or chunks
• impurities: ≤0.005 meq/g free acid (as HClO₄); ≤0.025 meq/g free alkali (as MgO); ≤8% water
• anion traces: chloride (Cl^-): ≤50 mg/kg; nitrate (NO₃^-): ≤100 mg/kg; sulfate (SO₄^2-): ≤500 mg/kg
• cation traces: Ca: ≤500 mg/kg; Cd: ≤5 mg/kg; Co: ≤5 mg/kg; Cr: ≤5 mg/kg; Cu: ≤5 mg/kg; Fe: ≤5 mg/kg; K: ≤500 mg/kg; Mn: ≤5 mg/kg; Na: ≤50 mg/kg; Ni: ≤5 mg/kg; Pb: ≤5 mg/kg; Zn: ≤5 mg/kg
• SMILES string: [Mg++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• InChI: 1S/2ClHO4.Mg/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2
• InChI key: MPCRDALPQLDDFX-UHFFFAOYSA-L

Description

General description

Magnesium perchlorate (Mg(ClO₄)₂) is widely used as drying agent for gases. It can remove water from gases (with no organic contaminants) at the rate of 0.001mgwater/l.[1]

Application

Magnesium perchlorate (Mg(ClO₄)₂) may be employed as a catalyst in the following studies:

• Preparation of α-aminophosphonates.[2]
• Enantioselective Diels-Alder reaction between cyclopentadiene and 3-acryloyl-1,3-oxazolin-2-one.[3]
• Preparation of imines and phenylhydrazones.[4]
• Protection of alcohols in the form of t-butyl ethers.[5]

Safety Information

• Pictograms: GHS03,GHS07
• Signal Word: Danger
• Hazard Statements: H272,H315,H319,H335
• Precautionary Statements: P210 - P220 - P261 - P264 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 5.1A - Strongly oxidizing hazardous materials
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable